DC Field | Value | Language |
---|---|---|
dc.contributor.author | Chung, I | ko |
dc.contributor.author | Do, J | ko |
dc.contributor.author | Canlas, CG | ko |
dc.contributor.author | Weliky, DP | ko |
dc.contributor.author | Kanatzidis, MG | ko |
dc.date.accessioned | 2019-04-15T16:32:20Z | - |
dc.date.available | 2019-04-15T16:32:20Z | - |
dc.date.created | 2013-05-06 | - |
dc.date.issued | 2004-05 | - |
dc.identifier.citation | INORGANIC CHEMISTRY, v.43, no.9, pp.2762 - 2764 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | http://hdl.handle.net/10203/255898 | - |
dc.description.abstract | The ternary alkali selenophosphates KPSe6 and RbPSe6 crystallize in the polar orthorhombic space group Pca2(1) with a = 11.7764(17) Angstrom, b = 6.8580(10) Angstrom, c = 11.4596(16) Angstrom, and Z = 4 for RbPSe6. CsPSe6 crystallizes in the monoclinic space group P2/n with a = 6.877(3) Angstrom, b = 12.713(4) Angstrom, c = 11.242(4) Angstrom, beta = 92.735(7)degrees, and Z= 4. All compounds feature the one-dimensional infinite chain of [PSe2(Se)(4)(-)], where each P atom is connected with Se-4(2-) bridge. These compounds show reversible glass-crystal transition, and P-31 NMR data suggest that crystallization and infinite [PSe6-] chain formation are coupled processes. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | METAL POLYSELENOPHOSPHATE FLUXES | - |
dc.subject | ANION | - |
dc.subject | FRAGMENTS | - |
dc.subject | BONDS | - |
dc.title | APSe(6) (A = k, Rb, and Cs): Polymeric selenophosphates with reversible phase-change properties | - |
dc.type | Article | - |
dc.identifier.wosid | 000221168000003 | - |
dc.identifier.scopusid | 2-s2.0-2142767362 | - |
dc.type.rims | ART | - |
dc.citation.volume | 43 | - |
dc.citation.issue | 9 | - |
dc.citation.beginningpage | 2762 | - |
dc.citation.endingpage | 2764 | - |
dc.citation.publicationname | INORGANIC CHEMISTRY | - |
dc.identifier.doi | 10.1021/ic035448q | - |
dc.contributor.localauthor | Chung, I | - |
dc.contributor.nonIdAuthor | Do, J | - |
dc.contributor.nonIdAuthor | Canlas, CG | - |
dc.contributor.nonIdAuthor | Weliky, DP | - |
dc.contributor.nonIdAuthor | Kanatzidis, MG | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | METAL POLYSELENOPHOSPHATE FLUXES | - |
dc.subject.keywordPlus | ANION | - |
dc.subject.keywordPlus | FRAGMENTS | - |
dc.subject.keywordPlus | BONDS | - |
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