Zn-containing porphyrin as a biomimetic light-harvesting molecule for biocatalyzed artificial photosynthesis
Among the porphyrin molecules with different metal insertion sites and functional ligands, Zn-porphyrin most efficiently regenerates NADH through photo-induced electron transfer in the presence of [Cp*Rh(bpy)H(2)O](2+), a rhodium-based electron mediator. Photochemical regeneration of NADH by Zn-porphyrin is successfully coupled with redox enzymatic synthesis under dark state conditions.
- Publisher
- Royal Soc Chemistry
- Issue Date
- 2011
- Language
- English
- Article Type
- Article
- Keywords
PHOTOINDUCED ELECTRON-TRANSFER; VISIBLE-LIGHT; SUPRAMOLECULAR SYSTEMS; NICOTINAMIDE COFACTOR; HYDROGEN-PRODUCTION; REGENERATION; EFFICIENT; METALLOPORPHYRIN; REDUCTION
- Citation
CHEMICAL COMMUNICATIONS, v.47, no.37, pp.10227 - 10229
- ISSN
- 1359-7345
- Appears in Collection
- MS-Journal Papers(저널논문)
- Files in This Item
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