Conversion of methane to ethylene using an Ir complex and phosphorus ylide as a methylene transfer reagent
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Zatsepin, Pavel | ko |
| dc.contributor.author | Ahn, Seihwan | ko |
| dc.contributor.author | Pudasaini, Bimal | ko |
| dc.contributor.author | Gau, Michael R. | ko |
| dc.contributor.author | Baik, Mu-Hyun | ko |
| dc.contributor.author | Mindiola, Daniel J. | ko |
| dc.date.accessioned | 2019-03-19T01:05:04Z | - |
| dc.date.available | 2019-03-19T01:05:04Z | - |
| dc.date.created | 2019-02-25 | - |
| dc.date.created | 2019-02-25 | - |
| dc.date.issued | 2019-02 | - |
| dc.identifier.citation | CHEMICAL COMMUNICATIONS, v.55, no.13, pp.1927 - 1930 | - |
| dc.identifier.issn | 1359-7345 | - |
| dc.identifier.uri | http://hdl.handle.net/10203/251498 | - |
| dc.description.abstract | Cp*(Me3P)Ir(CH3)(OTf), a complex known to reversibly activate CH4 and other hydrocarbons under mild conditions, reacts with the phosphorus ylide H2CPPh3 in THF to afford two major species [Cp*(Me3P)(Ph3P)Ir(CH2CH3)][OTf] and [Cp*(Me3P)Ir(H)(eta(2)-CH2CH2)][OTf]. Insertion of the ylide methylene group can also occur with Cp*(Me3P)Ir(Ph)(OTf) to afford the benzyl [Cp*(Me3P)(Ph3P)Ir(CH2-Ph)][OTf]. Theoretical studies suggest the intermediacy of an Ir(III)= CH2 species. | - |
| dc.language | English | - |
| dc.publisher | ROYAL SOC CHEMISTRY | - |
| dc.title | Conversion of methane to ethylene using an Ir complex and phosphorus ylide as a methylene transfer reagent | - |
| dc.type | Article | - |
| dc.identifier.wosid | 000458390000010 | - |
| dc.identifier.scopusid | 2-s2.0-85061133684 | - |
| dc.type.rims | ART | - |
| dc.citation.volume | 55 | - |
| dc.citation.issue | 13 | - |
| dc.citation.beginningpage | 1927 | - |
| dc.citation.endingpage | 1930 | - |
| dc.citation.publicationname | CHEMICAL COMMUNICATIONS | - |
| dc.identifier.doi | 10.1039/c8cc08761j | - |
| dc.contributor.localauthor | Baik, Mu-Hyun | - |
| dc.contributor.nonIdAuthor | Zatsepin, Pavel | - |
| dc.contributor.nonIdAuthor | Pudasaini, Bimal | - |
| dc.contributor.nonIdAuthor | Gau, Michael R. | - |
| dc.contributor.nonIdAuthor | Mindiola, Daniel J. | - |
| dc.description.isOpenAccess | N | - |
| dc.type.journalArticle | Article | - |
| dc.subject.keywordPlus | MIGRATORY INSERTION | - |
| dc.subject.keywordPlus | ACTIVATION | - |
| dc.subject.keywordPlus | METHYLIDENE | - |
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