DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jin, JungHo | - |
dc.contributor.author | Yang, SeungCheol | - |
dc.contributor.author | Bae, Byeong-Soo | - |
dc.date.accessioned | 2011-09-05T05:05:31Z | - |
dc.date.available | 2011-09-05T05:05:31Z | - |
dc.date.issued | 2011 | - |
dc.identifier.citation | Polymer Chemistry, Vol.2, No.1, pp.168-174 | en |
dc.identifier.issn | 1759-9954 | - |
dc.identifier.uri | http://hdl.handle.net/10203/25091 | - |
dc.description.abstract | The UV-induced cross-linked network structures of methacryl-oligosiloxane nanoclusters (MONCs) were analyzed with a hydrofluoric acid dissolution derived gel permeation chromatography technique (HF-GPC) to study their network structure-property relationships. With this method the oligosiloxane cores were dissolved in HF and the remaining organic tethers underwent GPC analysis to observe the tether species and characterize the original cross-linked network structures. It was found that the MONC nanocomposites have a highly cross-linked structure, resulting in oligosiloxane cores which are completely isolated by short methacryl chain segments (two-or three-armed methacryl tethers). This structural analysis was found to be consistent with the macroscale properties of MONC nanocomposites when characterized with thermal (TGA) and thermo-mechanical (DMA and TMA) analyses. | en |
dc.description.sponsorship | This work was supported by the National Research Foundation (NRF) of Korea funded by the Ministry of Education, Science and Technology (MEST) (No. R01-2007-000-20815-0 and CAFDC-20100009898). | en |
dc.language.iso | en_US | en |
dc.publisher | Royal Society of Chemistry | en |
dc.title | Network structure-property relationship in UV-cured organic/inorganic hybrid nanocomposites | en |
dc.type | Article | en |
dc.identifier.doi | 10.1039/c0py00148a | - |
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