DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Dong Jun | ko |
dc.contributor.author | Yoo, Dong-Joo | ko |
dc.contributor.author | Otley, Michael T. | ko |
dc.contributor.author | Prokofjevs, Aleksandrs | ko |
dc.contributor.author | Pezzato, Cristian | ko |
dc.contributor.author | Owczarek, Magdalena | ko |
dc.contributor.author | Lee, Seung Jong | ko |
dc.contributor.author | Choi, Jang Wook | ko |
dc.contributor.author | Stoddart, J. Fraser | ko |
dc.date.accessioned | 2019-02-20T05:12:30Z | - |
dc.date.available | 2019-02-20T05:12:30Z | - |
dc.date.created | 2019-02-11 | - |
dc.date.issued | 2019-01 | - |
dc.identifier.citation | NATURE ENERGY, v.4, no.1, pp.51 - 59 | - |
dc.identifier.issn | 2058-7546 | - |
dc.identifier.uri | http://hdl.handle.net/10203/250364 | - |
dc.description.abstract | Since aluminium is one of the most widely available elements in Earth's crust, developing rechargeable aluminium batteries offers an ideal opportunity to deliver cells with high energy-to-price ratios. Nevertheless, finding appropriate host electrodes for insertion of aluminium (complex) ions remains a fundamental challenge. Here, we demonstrate a strategy for designing active materials for rechargeable aluminium batteries. This strategy entails the use of redox-active triangular phenanthrenequinone-based macrocycles, which form layered superstructures resulting in the reversible insertion and extraction of a cationic aluminium complex. This architecture exhibits an outstanding electrochemical performance with a reversible capacity of 110 mA h g(-1) along with a superior cyclability of up to 5,000 cycles. Furthermore, electrodes composed of these macrocycles blended with graphite flakes result in higher specific capacity, electronic conductivity and areal loading. These findings constitute a major advance in the design of rechargeable aluminium batteries and represent a good starting point for addressing affordable large-scale energy storage. | - |
dc.language | English | - |
dc.publisher | NATURE PUBLISHING GROUP | - |
dc.title | Rechargeable aluminium organic batteries | - |
dc.type | Article | - |
dc.identifier.wosid | 000455821500014 | - |
dc.identifier.scopusid | 2-s2.0-85058033571 | - |
dc.type.rims | ART | - |
dc.citation.volume | 4 | - |
dc.citation.issue | 1 | - |
dc.citation.beginningpage | 51 | - |
dc.citation.endingpage | 59 | - |
dc.citation.publicationname | NATURE ENERGY | - |
dc.identifier.doi | 10.1038/s41560-018-0291-0 | - |
dc.contributor.nonIdAuthor | Kim, Dong Jun | - |
dc.contributor.nonIdAuthor | Yoo, Dong-Joo | - |
dc.contributor.nonIdAuthor | Otley, Michael T. | - |
dc.contributor.nonIdAuthor | Prokofjevs, Aleksandrs | - |
dc.contributor.nonIdAuthor | Pezzato, Cristian | - |
dc.contributor.nonIdAuthor | Owczarek, Magdalena | - |
dc.contributor.nonIdAuthor | Choi, Jang Wook | - |
dc.contributor.nonIdAuthor | Stoddart, J. Fraser | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
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