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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Stereocontrolled, Divergent, Al(III)-Catalyzed Coupling of Chiral N-Aryl Epoxy Amines and CO2

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dc.contributor.authorLee, Yuseopko
dc.contributor.authorChoi, Jonghoonko
dc.contributor.authorKim, Hyunwooko
dc.date.accessioned2018-10-19T00:31:52Z-
dc.date.available2018-10-19T00:31:52Z-
dc.date.created2018-09-19-
dc.date.created2018-09-19-
dc.date.created2018-09-19-
dc.date.issued2018-08-
dc.identifier.citationORGANIC LETTERS, v.20, no.16, pp.5036 - 5039-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10203/245923-
dc.description.abstractA divergent coupling reaction was achieved between N-aryl epoxy amines and CO2. By using two different cocatalysts, tetrabutylammonium iodide (TBAI) or 4-dimethylaminopyridine (DMAP) together with an Al(III) Lewis acid, cyclic carbonates or oxazolidinones were selectively produced through two distinct reaction pathways, respectively. The proposed reaction mechanism was supported by the stereochemical determination of the products. A gram-scale production of Linezolid was successfully achieved.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.titleStereocontrolled, Divergent, Al(III)-Catalyzed Coupling of Chiral N-Aryl Epoxy Amines and CO2-
dc.typeArticle-
dc.identifier.wosid000442454900071-
dc.identifier.scopusid2-s2.0-85051741015-
dc.type.rimsART-
dc.citation.volume20-
dc.citation.issue16-
dc.citation.beginningpage5036-
dc.citation.endingpage5039-
dc.citation.publicationnameORGANIC LETTERS-
dc.identifier.doi10.1021/acs.orglett.8b02186-
dc.contributor.localauthorKim, Hyunwoo-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordPlusHYDROLYTIC KINETIC RESOLUTION-
dc.subject.keywordPlusCARBON-DIOXIDE-
dc.subject.keywordPlusCYCLIC CARBONATES-
dc.subject.keywordPlusSELECTIVE FORMATION-
dc.subject.keywordPlusEPOXIDES-
dc.subject.keywordPlusCOPOLYMERIZATION-
dc.subject.keywordPlusCATALYSTS-
dc.subject.keywordPlusCYCLOADDITION-
dc.subject.keywordPlusCOMPLEXES-
dc.subject.keywordPlusMECHANISM-
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