DC Field | Value | Language |
---|---|---|
dc.contributor.author | Gunasekar, Gunniya Hariyanandam | ko |
dc.contributor.author | Park, Kwangho | ko |
dc.contributor.author | Jeong, Hyeonseok | ko |
dc.contributor.author | Jung, Kwang-Deog | ko |
dc.contributor.author | Park, Kiyoung | ko |
dc.contributor.author | Yoon, Sungho | ko |
dc.date.accessioned | 2018-08-20T08:08:21Z | - |
dc.date.available | 2018-08-20T08:08:21Z | - |
dc.date.created | 2018-08-13 | - |
dc.date.created | 2018-08-13 | - |
dc.date.created | 2018-08-13 | - |
dc.date.issued | 2018-07 | - |
dc.identifier.citation | CATALYSTS, v.8, no.7 | - |
dc.identifier.issn | 2073-4344 | - |
dc.identifier.uri | http://hdl.handle.net/10203/244980 | - |
dc.description.abstract | The catalytic reactivity of molecular Rh(III)/Ir(III) catalysts immobilized on two- and three-dimensional Bipyridine-based Covalent Triazine Frameworks (bpy-CTF) for the hydrogenation of CO2 to formate has been described. The heterogenized Ir complex demonstrated superior catalytic efficiency over its Rh counterpart. The Ir catalyst immobilized on two-dimensional bpy-CTF showed an improved turnover frequency and turnover number compared to its three-dimensional counterpart. The two-dimensional Ir catalyst produced a maximum formate concentration of 1.8 M and maintained its catalytic efficiency over five consecutive runs with an average of 92% in each cycle. The reduced activity after recycling was studied by density functional theory calculations, and a plausible leaching pathway along with a rational catalyst design guidance have been proposed. | - |
dc.language | English | - |
dc.publisher | MDPI | - |
dc.title | Molecular Rh(III) and Ir(III) Catalysts Immobilized on Bipyridine-Based Covalent Triazine Frameworks for the Hydrogenation of CO2 to Formate | - |
dc.type | Article | - |
dc.identifier.wosid | 000440016400042 | - |
dc.identifier.scopusid | 2-s2.0-85050925397 | - |
dc.type.rims | ART | - |
dc.citation.volume | 8 | - |
dc.citation.issue | 7 | - |
dc.citation.publicationname | CATALYSTS | - |
dc.identifier.doi | 10.3390/catal8070295 | - |
dc.contributor.localauthor | Park, Kiyoung | - |
dc.contributor.nonIdAuthor | Gunasekar, Gunniya Hariyanandam | - |
dc.contributor.nonIdAuthor | Park, Kwangho | - |
dc.contributor.nonIdAuthor | Jeong, Hyeonseok | - |
dc.contributor.nonIdAuthor | Jung, Kwang-Deog | - |
dc.contributor.nonIdAuthor | Yoon, Sungho | - |
dc.description.isOpenAccess | Y | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | heterogenization on covalent triazine frameworks | - |
dc.subject.keywordAuthor | immobilized bipyridine complexes | - |
dc.subject.keywordAuthor | heterogenized Ir and Rh complexes | - |
dc.subject.keywordAuthor | heterogeneous CO2 hydrogenation catalyst | - |
dc.subject.keywordAuthor | leaching pathway of heterogenized half-sandwich complexes | - |
dc.subject.keywordPlus | TERTIARY AMINE MEDIUM | - |
dc.subject.keywordPlus | CARBON-DIOXIDE HYDROGENATION | - |
dc.subject.keywordPlus | LOW-TEMPERATURE OXIDATION | - |
dc.subject.keywordPlus | FORMIC-ACID | - |
dc.subject.keywordPlus | IRIDIUM COMPLEX | - |
dc.subject.keywordPlus | HETEROGENEOUS CATALYST | - |
dc.subject.keywordPlus | IONOTHERMAL SYNTHESIS | - |
dc.subject.keywordPlus | AMBIENT-TEMPERATURE | - |
dc.subject.keywordPlus | RUTHENIUM CATALYST | - |
dc.subject.keywordPlus | ROOM-TEMPERATURE | - |
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