Microporous metal organic framework-based copolymers with efficient gas adsorption capability and high temporal stability

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dc.contributor.authorJung, Jong-Yeongko
dc.contributor.authorKo, Sung-Hoko
dc.contributor.authorPark, Su-Limko
dc.contributor.authorShin, Hun-Heeko
dc.contributor.authorOh, Hyun-Changko
dc.contributor.authorRyu, Jong-Wanko
dc.contributor.authorLee, Seung-Chulko
dc.contributor.authorKwon, O-Pilko
dc.contributor.authorChoi, Eun-Youngko
dc.date.accessioned2018-01-22T02:05:22Z-
dc.date.available2018-01-22T02:05:22Z-
dc.date.created2017-12-18-
dc.date.created2017-12-18-
dc.date.issued2017-11-
dc.identifier.citationMACROMOLECULAR RESEARCH, v.25, no.11, pp.1100 - 1104-
dc.identifier.issn1598-5032-
dc.identifier.urihttp://hdl.handle.net/10203/237176-
dc.description.abstractWe report new microporous metal-organic 3D coordinated copolymers that exhibit both highly efficient gas adsorption capability and high temporal stability. The Zn-coordinated copolymers (MBCn) were prepared by mixing two organic ligands at various molar ratios: the widely used benzenedicarboxylate (BDC) and its analogous Cn-acid with non-polar alkoxy side chains of various lengths. All MBCn copolymers bearing alkoxy side chains exhibited identical framework structures to that of MOF-5 prepared with only the BDC ligand. Interestingly, compared to MOF-5, MBCn copolymers exhibited up to three times higher gas adsorption properties and higher temporal structural stability. Therefore, copolymerization with organic ligands bearing alkoxy side chains is a promising strategy for the development of new microporous metal-organic hybrid materials.-
dc.languageEnglish-
dc.publisherSPRINGER-
dc.subjectHYDROGEN STORAGE-
dc.subjectFUNCTIONAL-GROUPS-
dc.subjectMOF-5-
dc.subjectMETHANE-
dc.subjectDESIGN-
dc.subjectWATER-
dc.titleMicroporous metal organic framework-based copolymers with efficient gas adsorption capability and high temporal stability-
dc.typeArticle-
dc.identifier.wosid000417079300008-
dc.identifier.scopusid2-s2.0-85029585657-
dc.type.rimsART-
dc.citation.volume25-
dc.citation.issue11-
dc.citation.beginningpage1100-
dc.citation.endingpage1104-
dc.citation.publicationnameMACROMOLECULAR RESEARCH-
dc.identifier.doi10.1007/s13233-017-5147-0-
dc.contributor.nonIdAuthorJung, Jong-Yeong-
dc.contributor.nonIdAuthorKo, Sung-Ho-
dc.contributor.nonIdAuthorPark, Su-Lim-
dc.contributor.nonIdAuthorShin, Hun-Hee-
dc.contributor.nonIdAuthorOh, Hyun-Chang-
dc.contributor.nonIdAuthorRyu, Jong-Wan-
dc.contributor.nonIdAuthorLee, Seung-Chul-
dc.contributor.nonIdAuthorKwon, O-Pil-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorcoordination polymers-
dc.subject.keywordAuthorcopolymers-
dc.subject.keywordAuthorgas adsorption-
dc.subject.keywordAuthormetal-organic frameworks-
dc.subject.keywordAuthormetallopolymers-
dc.subject.keywordPlusHYDROGEN STORAGE-
dc.subject.keywordPlusFUNCTIONAL-GROUPS-
dc.subject.keywordPlusMOF-5-
dc.subject.keywordPlusMETHANE-
dc.subject.keywordPlusDESIGN-
dc.subject.keywordPlusWATER-
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