DC Field | Value | Language |
---|---|---|
dc.contributor.author | Guo, Jia | ko |
dc.contributor.author | Xu, Yanhong | ko |
dc.contributor.author | Jin, Shangbin | ko |
dc.contributor.author | Chen, Long | ko |
dc.contributor.author | Kaji, Toshihiko | ko |
dc.contributor.author | Honsho, Yoshihito | ko |
dc.contributor.author | Addicoat, Matthew A. | ko |
dc.contributor.author | Kim, Jangbae | ko |
dc.contributor.author | Saeki, Akinori | ko |
dc.contributor.author | Ihee, Hyotcherl | ko |
dc.contributor.author | Seki, Shu | ko |
dc.contributor.author | Irle, Stephan | ko |
dc.contributor.author | Hiramoto, Masahiro | ko |
dc.contributor.author | Gao, Jia | ko |
dc.contributor.author | Jiang, Donglin | ko |
dc.date.accessioned | 2017-04-17T08:15:22Z | - |
dc.date.available | 2017-04-17T08:15:22Z | - |
dc.date.created | 2014-01-02 | - |
dc.date.created | 2014-01-02 | - |
dc.date.issued | 2013-11 | - |
dc.identifier.citation | NATURE COMMUNICATIONS, v.4 | - |
dc.identifier.issn | 2041-1723 | - |
dc.identifier.uri | http://hdl.handle.net/10203/223384 | - |
dc.description.abstract | Covalent organic frameworks are a class of crystalline organic porous materials that can utilize pi-pi-stacking interactions as a driving force for the crystallization of polygonal sheets to form layered frameworks and ordered pores. However, typical examples are chemically unstable and lack intrasheet pi-conjugation, thereby significantly limiting their applications. Here we report a chemically stable, electronically conjugated organic framework with topologically designed wire frameworks and open nanochannels, in which the pi conjugation-spans the two-dimensional sheets. Our framework permits inborn periodic ordering of conjugated chains in all three dimensions and exhibits a striking combination of properties: chemical stability, extended pi-delocalization, ability to host guest molecules and hole mobility. We show that the pi-conjugated organic framework is useful for high on-off ratio photoswitches and photovoltaic cells. Therefore, this strategy may constitute a step towards realizing ordered semiconducting porous materials for innovations based on two-dimensionally extended pi systems. | - |
dc.language | English | - |
dc.publisher | NATURE PUBLISHING GROUP | - |
dc.subject | TRIAZINE-BASED FRAMEWORKS | - |
dc.subject | MICROPOROUS POLYMERS | - |
dc.subject | COVALENT | - |
dc.subject | CRYSTALLINE | - |
dc.subject | ELECTRON | - |
dc.subject | HETEROJUNCTIONS | - |
dc.subject | FLUORESCENT | - |
dc.subject | CONDUCTION | - |
dc.subject | EFFICIENT | - |
dc.subject | POROSITY | - |
dc.title | Conjugated organic framework with three-dimensionally ordered stable structure and delocalized pi clouds | - |
dc.type | Article | - |
dc.identifier.wosid | 000328023000007 | - |
dc.identifier.scopusid | 2-s2.0-84887732334 | - |
dc.type.rims | ART | - |
dc.citation.volume | 4 | - |
dc.citation.publicationname | NATURE COMMUNICATIONS | - |
dc.identifier.doi | 10.1038/ncomms3736 | - |
dc.contributor.localauthor | Ihee, Hyotcherl | - |
dc.contributor.nonIdAuthor | Guo, Jia | - |
dc.contributor.nonIdAuthor | Xu, Yanhong | - |
dc.contributor.nonIdAuthor | Jin, Shangbin | - |
dc.contributor.nonIdAuthor | Chen, Long | - |
dc.contributor.nonIdAuthor | Kaji, Toshihiko | - |
dc.contributor.nonIdAuthor | Honsho, Yoshihito | - |
dc.contributor.nonIdAuthor | Addicoat, Matthew A. | - |
dc.contributor.nonIdAuthor | Kim, Jangbae | - |
dc.contributor.nonIdAuthor | Saeki, Akinori | - |
dc.contributor.nonIdAuthor | Seki, Shu | - |
dc.contributor.nonIdAuthor | Irle, Stephan | - |
dc.contributor.nonIdAuthor | Hiramoto, Masahiro | - |
dc.contributor.nonIdAuthor | Gao, Jia | - |
dc.contributor.nonIdAuthor | Jiang, Donglin | - |
dc.description.isOpenAccess | Y | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | TRIAZINE-BASED FRAMEWORKS | - |
dc.subject.keywordPlus | MICROPOROUS POLYMERS | - |
dc.subject.keywordPlus | COVALENT | - |
dc.subject.keywordPlus | CRYSTALLINE | - |
dc.subject.keywordPlus | ELECTRON | - |
dc.subject.keywordPlus | HETEROJUNCTIONS | - |
dc.subject.keywordPlus | FLUORESCENT | - |
dc.subject.keywordPlus | CONDUCTION | - |
dc.subject.keywordPlus | EFFICIENT | - |
dc.subject.keywordPlus | POROSITY | - |
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