DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Kiho | ko |
dc.contributor.author | Min, Minsik | ko |
dc.contributor.author | Hong, Sungwoo | ko |
dc.date.accessioned | 2017-04-17T07:26:58Z | - |
dc.date.available | 2017-04-17T07:26:58Z | - |
dc.date.created | 2017-04-10 | - |
dc.date.created | 2017-04-10 | - |
dc.date.issued | 2017-03 | - |
dc.identifier.citation | ADVANCED SYNTHESIS & CATALYSIS, v.359, no.5, pp.848 - 852 | - |
dc.identifier.issn | 1615-4150 | - |
dc.identifier.uri | http://hdl.handle.net/10203/223240 | - |
dc.description.abstract | Irradiation of 9-ester-substituted anthracenes with visible light results in the formation of endoperoxides in the absence of a photocatalyst, which further undergo base-assisted fragmentation to afford anthraquinones. The excited state species of anthracene generated by energy transfer, interacts with O-3(2) to afford O-1(2) by energy transfer and undergoes cycloaddition with O-1(2). By employing palladium(II)-catalyzed and visible light-mediated transformations, we have developed an efficient synthetic protocol for accessing diverse anthraquinones from readily available diaryl carboxylic acids. The optimal result was obtained with palladium(II) acetate, Ac-Ile-OH, benzoquinone and potassium carbonate in tert-amyl alcohol under O-2 at 90 degrees C with irradiation from a 30 W fluorescent light bulb. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | ORGANIC-COMPOUNDS | - |
dc.subject | ALPHA-ARYLATION | - |
dc.subject | ACETIC-ACID | - |
dc.subject | DERIVATIVES | - |
dc.subject | ANTHRACENE | - |
dc.subject | PHOTOOXYGENATION | - |
dc.subject | PHOTOOXIDATION | - |
dc.subject | OXIDATION | - |
dc.subject | ESTERS | - |
dc.subject | OXYGEN | - |
dc.title | Efficient Synthesis of Anthraquinones from Diaryl Carboxylic Acids via Palladium(II)-Catalyzed and Visible Light-Mediated Transformations | - |
dc.type | Article | - |
dc.identifier.wosid | 000396631700011 | - |
dc.identifier.scopusid | 2-s2.0-85008263831 | - |
dc.type.rims | ART | - |
dc.citation.volume | 359 | - |
dc.citation.issue | 5 | - |
dc.citation.beginningpage | 848 | - |
dc.citation.endingpage | 852 | - |
dc.citation.publicationname | ADVANCED SYNTHESIS & CATALYSIS | - |
dc.identifier.doi | 10.1002/adsc.201601057 | - |
dc.contributor.localauthor | Hong, Sungwoo | - |
dc.contributor.nonIdAuthor | Min, Minsik | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Palladium | - |
dc.subject.keywordAuthor | visible light | - |
dc.subject.keywordAuthor | anthraquinone | - |
dc.subject.keywordAuthor | singlet oxygen | - |
dc.subject.keywordAuthor | photooxidation | - |
dc.subject.keywordPlus | ORGANIC-COMPOUNDS | - |
dc.subject.keywordPlus | ALPHA-ARYLATION | - |
dc.subject.keywordPlus | ACETIC-ACID | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | ANTHRACENE | - |
dc.subject.keywordPlus | PHOTOOXYGENATION | - |
dc.subject.keywordPlus | PHOTOOXIDATION | - |
dc.subject.keywordPlus | OXIDATION | - |
dc.subject.keywordPlus | ESTERS | - |
dc.subject.keywordPlus | OXYGEN | - |
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