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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Metal- and oxidant-free S-P(O) bond construction via direct coupling of P(O) H with sulfinic acids

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dc.contributor.authorMoon, Youngtaekko
dc.contributor.authorMoon, Yonghoonko
dc.contributor.authorChoi, Hangyeolko
dc.contributor.authorHong, Sungwooko
dc.date.accessioned2017-04-14T08:14:09Z-
dc.date.available2017-04-14T08:14:09Z-
dc.date.created2017-04-03-
dc.date.created2017-04-03-
dc.date.created2017-04-03-
dc.date.issued2017-02-
dc.identifier.citationGREEN CHEMISTRY, v.19, no.4, pp.1005 - 1013-
dc.identifier.issn1463-9262-
dc.identifier.urihttp://hdl.handle.net/10203/223027-
dc.description.abstractWe have developed a simple and convenient method for S-P(O) bond formation between R2P(O) H and sulfinic acids under metal-, oxidant-, and halogen-free conditions. The current method is compatible with a broad range of substituents on various substrates including halogens and heterocyclic moieties. The synthetic potential of this method was further highlighted by the expeditious synthesis of optically active P-chiral phosphorothioates via stereospecific coupling.-
dc.languageEnglish-
dc.publisherROYAL SOC CHEMISTRY-
dc.subjectARYLSULFINIC ACIDS-
dc.subjectAEROBIC DIFUNCTIONALIZATION-
dc.subjectALLYLIC SULFONES-
dc.subjectPHOSPHINE OXIDES-
dc.subjectHIGHLY EFFICIENT-
dc.subjectVINYL SULFONES-
dc.subjectGENERAL-METHOD-
dc.subjectS-ARYL-
dc.subjectDERIVATIVES-
dc.subjectALKYNES-
dc.titleMetal- and oxidant-free S-P(O) bond construction via direct coupling of P(O) H with sulfinic acids-
dc.typeArticle-
dc.identifier.wosid000395866600016-
dc.identifier.scopusid2-s2.0-85024095851-
dc.type.rimsART-
dc.citation.volume19-
dc.citation.issue4-
dc.citation.beginningpage1005-
dc.citation.endingpage1013-
dc.citation.publicationnameGREEN CHEMISTRY-
dc.identifier.doi10.1039/c6gc03285k-
dc.contributor.localauthorHong, Sungwoo-
dc.contributor.nonIdAuthorMoon, Youngtaek-
dc.contributor.nonIdAuthorChoi, Hangyeol-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordPlusARYLSULFINIC ACIDS-
dc.subject.keywordPlusAEROBIC DIFUNCTIONALIZATION-
dc.subject.keywordPlusALLYLIC SULFONES-
dc.subject.keywordPlusPHOSPHINE OXIDES-
dc.subject.keywordPlusHIGHLY EFFICIENT-
dc.subject.keywordPlusVINYL SULFONES-
dc.subject.keywordPlusGENERAL-METHOD-
dc.subject.keywordPlusS-ARYL-
dc.subject.keywordPlusDERIVATIVES-
dc.subject.keywordPlusALKYNES-
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