DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, JH | ko |
dc.contributor.author | Lamrani, M | ko |
dc.contributor.author | Hwang, JW | ko |
dc.contributor.author | Do, Youngkyu | ko |
dc.date.accessioned | 2007-11-28T02:06:08Z | - |
dc.date.available | 2007-11-28T02:06:08Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 1998-12 | - |
dc.identifier.citation | INORGANICA CHIMICA ACTA, v.283, no.1, pp.145 - 150 | - |
dc.identifier.issn | 0020-1693 | - |
dc.identifier.uri | http://hdl.handle.net/10203/2203 | - |
dc.description.abstract | For the first time, the structure of the half-sandwich complex [(C2B9H11)Mo(CO)(3)](2-) (1) has been determined. The addition of sulfur donor ligands, such as aldrithiol ((C5H4NS)(2)) and tetraethylthiuram disulfide ((Et2NS)(2)S-2), leads to the partial oxidative decarbonylation of 1 producing mixed half-sandwich complexes, [(C2B9H11)Mo(CO)(2)(S2CNEt2)].(PPN) (2.PPN) (PPN; bis-(triphenylphosphoranylidene)ammonium) and [(C2B9H11)Mo(Co)(2)(C5H4NS)].(NMe4) (3.NMe4). These compounds were characterized both spectroscopically and structurally. Complexes 2 and 3 contain a Mo(II) center in a pseudo pyramidal geometry. Compound 1.(NMe4)(2) is fundamental in affording an entry into the chemistry of new molybdacarboranes with higher formal oxidation states. (C) 1998 Elsevier Science S.A. All rights reserved. | - |
dc.description.sponsorship | the Korea Science and Engineering Foundation | en |
dc.language | English | - |
dc.language.iso | en_US | en |
dc.publisher | ELSEVIER SCIENCE SA | - |
dc.subject | STRUCTURAL CHARACTERIZATION | - |
dc.subject | MO-S | - |
dc.subject | COMPLEXES | - |
dc.subject | LIGANDS | - |
dc.subject | DICARBOLLIDE | - |
dc.subject | EXTRACTION | - |
dc.subject | CESIUM | - |
dc.title | Oxidation of tricarbonylmolybdacarborane. 2. Oxidative decarbonylalion with various sulfur donors | - |
dc.type | Article | - |
dc.identifier.wosid | 000077022200020 | - |
dc.identifier.scopusid | 2-s2.0-0001141145 | - |
dc.type.rims | ART | - |
dc.citation.volume | 283 | - |
dc.citation.issue | 1 | - |
dc.citation.beginningpage | 145 | - |
dc.citation.endingpage | 150 | - |
dc.citation.publicationname | INORGANICA CHIMICA ACTA | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Do, Youngkyu | - |
dc.contributor.nonIdAuthor | Kim, JH | - |
dc.contributor.nonIdAuthor | Lamrani, M | - |
dc.contributor.nonIdAuthor | Hwang, JW | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | molybdacarborane | - |
dc.subject.keywordAuthor | oxidative decarbonylation | - |
dc.subject.keywordPlus | STRUCTURAL CHARACTERIZATION | - |
dc.subject.keywordPlus | MO-S | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | LIGANDS | - |
dc.subject.keywordPlus | DICARBOLLIDE | - |
dc.subject.keywordPlus | EXTRACTION | - |
dc.subject.keywordPlus | CESIUM | - |
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