A side-scattering technique for investigating the inner microstructure of photonic crystal fibers (PCFs) is reported. Multiple scattering is reduced by filling the hollow PCF channels with index-matching fluid. The scattered signal is measured for fixed angles of incidence and detection while the fiber is rotated. A pattern of peaks, unique to each PCF, whether solid or hollow core, correlates closely with the symmetry planes of the PCF structure. As an example of the technique, the twist profile of a structural rocking filter is directly measured. (C) 2011 Optical Society of America