DC Field | Value | Language |
---|---|---|
dc.contributor.author | Yoo, Changho | ko |
dc.contributor.author | Lee, Yunho | ko |
dc.date.accessioned | 2017-01-12T07:13:20Z | - |
dc.date.available | 2017-01-12T07:13:20Z | - |
dc.date.created | 2016-09-20 | - |
dc.date.created | 2016-09-20 | - |
dc.date.issued | 2017 | - |
dc.identifier.citation | CHEMICAL SCIENCE, v.8, no.1, pp.600 - 605 | - |
dc.identifier.issn | 2041-6520 | - |
dc.identifier.uri | http://hdl.handle.net/10203/218289 | - |
dc.description.abstract | The degree of CO2 activation can be tuned by incorporating a distinct electronic coordination environment at the nickel center. A mononuclear nickel carboxylate species (Ni-CO2, 3) and a dinuclear nickel-iron carboxylate species (Ni-CO2-Fe, 5) were prepared. The structure of 3 reveals a rare eta(1)-kC binding mode of CO2, while that of 5 shows bridging CO2 binding (mu(2)-kC: k(2)O,O') between the nickel and iron, presented as the first example of a nickel-mu-CO2-iron species. The structural analyses of 3 and 5 based on XRD and DFT data reveal a higher degree of CO2 activation in 5, imparted by the additional interaction with an iron ion. | - |
dc.language | English | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.subject | MONOXIDE DEHYDROGENASE | - |
dc.subject | CO DEHYDROGENASE | - |
dc.subject | ACTIVE-SITE | - |
dc.subject | CUBANE-TYPE | - |
dc.subject | IRON-TIN | - |
dc.subject | COMPLEXES | - |
dc.subject | ACTIVATION | - |
dc.subject | REDUCTION | - |
dc.subject | CLUSTER | - |
dc.subject | SPECTROSCOPY | - |
dc.title | Carbon dioxide binding at a Ni/Fe center: synthesis and characterization of Ni(eta(1)-CO2-kappa C) and Ni-mu-CO2- kappa C:kappa O-2,O '-Fe | - |
dc.type | Article | - |
dc.identifier.wosid | 000391454500071 | - |
dc.identifier.scopusid | 2-s2.0-85006981001 | - |
dc.type.rims | ART | - |
dc.citation.volume | 8 | - |
dc.citation.issue | 1 | - |
dc.citation.beginningpage | 600 | - |
dc.citation.endingpage | 605 | - |
dc.citation.publicationname | CHEMICAL SCIENCE | - |
dc.identifier.doi | 10.1039/C6SC03450K | - |
dc.contributor.localauthor | Lee, Yunho | - |
dc.description.isOpenAccess | Y | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | MONOXIDE DEHYDROGENASE | - |
dc.subject.keywordPlus | CO DEHYDROGENASE | - |
dc.subject.keywordPlus | ACTIVE-SITE | - |
dc.subject.keywordPlus | CUBANE-TYPE | - |
dc.subject.keywordPlus | IRON-TIN | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | ACTIVATION | - |
dc.subject.keywordPlus | REDUCTION | - |
dc.subject.keywordPlus | CLUSTER | - |
dc.subject.keywordPlus | SPECTROSCOPY | - |
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