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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

A Facile Access to Primary Alkylamines and Anilines via Ir(III)-Catalyzed C-H Amidation Using Azidoformates

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dc.contributor.authorKim, Hyunwooko
dc.contributor.authorPark, Gyeongtaeko
dc.contributor.authorPark, Juhyeonko
dc.contributor.authorChang, Sukbokko
dc.date.accessioned2016-10-07T09:26:44Z-
dc.date.available2016-10-07T09:26:44Z-
dc.date.created2016-10-05-
dc.date.created2016-10-05-
dc.date.issued2016-09-
dc.identifier.citationACS CATALYSIS, v.6, no.9, pp.5922 - 5929-
dc.identifier.issn2155-5435-
dc.identifier.urihttp://hdl.handle.net/10203/213212-
dc.description.abstractDescribed herein is the development of Ir(III)-catalyzed direct C-H amidation using azidoformates as a readily deprotectable amino source. Substrates with unactivated methyl C(sp(3))-H and aromatic or olefinic C(sp(2)) -H bonds were smoothly reacted by the iridium-based catalyst system to provide the corresponding primary alkylamines and anilines upon the subsequent removal of N-protecting groups, such as Boc, Fmoc, Cbz, pNZ, or Troc. A brief mechanistic study and synthetic applications are also presented-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectIRON(II)-MEDIATED NITRENE TRANSFER-
dc.subjectTRANSITION-METAL-COMPLEXES-
dc.subjectCATALYZED DIRECT AMINATION-
dc.subjectBOND-FORMING REACTIONS-
dc.subjectROOM-TEMPERATURE-
dc.subjectNITROGEN-SOURCE-
dc.subjectARYL HALIDES-
dc.subjectINTERMOLECULAR AMIDATION-
dc.subject2,2,2-TRICHLOROETHOXYCARBONYL AZIDE-
dc.subjectASYMMETRIC CATALYSIS-
dc.titleA Facile Access to Primary Alkylamines and Anilines via Ir(III)-Catalyzed C-H Amidation Using Azidoformates-
dc.typeArticle-
dc.identifier.wosid000382714000031-
dc.identifier.scopusid2-s2.0-84984863513-
dc.type.rimsART-
dc.citation.volume6-
dc.citation.issue9-
dc.citation.beginningpage5922-
dc.citation.endingpage5929-
dc.citation.publicationnameACS CATALYSIS-
dc.identifier.doi10.1021/acscatal.6b01869-
dc.contributor.localauthorChang, Sukbok-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorC-H amidation-
dc.subject.keywordAuthoriridium catalysis-
dc.subject.keywordAuthorazidoformates-
dc.subject.keywordAuthorprimary alkylamines-
dc.subject.keywordAuthorprimary anilines-
dc.subject.keywordPlusIRON(II)-MEDIATED NITRENE TRANSFER-
dc.subject.keywordPlusTRANSITION-METAL-COMPLEXES-
dc.subject.keywordPlusCATALYZED DIRECT AMINATION-
dc.subject.keywordPlusBOND-FORMING REACTIONS-
dc.subject.keywordPlusROOM-TEMPERATURE-
dc.subject.keywordPlusNITROGEN-SOURCE-
dc.subject.keywordPlusARYL HALIDES-
dc.subject.keywordPlusINTERMOLECULAR AMIDATION-
dc.subject.keywordPlus2,2,2-TRICHLOROETHOXYCARBONYL AZIDE-
dc.subject.keywordPlusASYMMETRIC CATALYSIS-
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