The unusual hydridicity of a cobalt bound Si-H moiety
A paramagnetic cobalt-SiH intermediate possessing the Co-(eta(1)-H-Si) moiety was studied using various spectroscopic techniques. Frozen solution ENDOR experiments show a Co-H distance of similar to 1.53 angstrom and a Si-Co-H angle of similar to 15 degrees, whereas XRD data suggest a TBP geometry about a Co(II) centre. Its stepwise deprotonation with base followed by dehalogenation was identified experimentally and theoretically.
- Publisher
- ROYAL SOC CHEMISTRY
- Issue Date
- 2016
- Language
- English
- Article Type
- Article
- Keywords
SIGMA-BOND METATHESIS; TRANSITION-METAL-COMPLEXES; EFFECTIVE CORE POTENTIALS; MOLECULAR CALCULATIONS; SPECTROSCOPIC PROPERTIES; STRUCTURAL-ANALYSIS; OXIDATIVE ADDITION; SOLUTION ACIDITY; SILYL COMPLEXES; LIGAND
- Citation
CHEMICAL COMMUNICATIONS, v.52, no.60, pp.9367 - 9370
- ISSN
- 1359-7345
- Appears in Collection
- CH-Journal Papers(저널논문)
- Files in This Item
- There are no files associated with this item.
This item is cited by other documents in WoS
| ⊙ Detail Information in WoSⓡ | Click to see |  |
| ⊙ Cited 17 items in WoS | Click to see citing articles in |  |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.