DC Field | Value | Language |
---|---|---|
dc.contributor.author | Talapaneni, Siddulu Naidu | ko |
dc.contributor.author | Kim, Daeok | ko |
dc.contributor.author | Barin, Gokhan | ko |
dc.contributor.author | Buyukcakir, Onur | ko |
dc.contributor.author | Je, Sang Hyun | ko |
dc.contributor.author | Coskun, Ali | ko |
dc.date.accessioned | 2016-09-06T08:56:27Z | - |
dc.date.available | 2016-09-06T08:56:27Z | - |
dc.date.created | 2016-08-02 | - |
dc.date.created | 2016-08-02 | - |
dc.date.created | 2016-08-02 | - |
dc.date.issued | 2016-06 | - |
dc.identifier.citation | CHEMISTRY OF MATERIALS, v.28, no.12, pp.4460 - 4466 | - |
dc.identifier.issn | 0897-4756 | - |
dc.identifier.uri | http://hdl.handle.net/10203/212405 | - |
dc.description.abstract | We present an efficient strategy for the preparation of conjugated microporous polymers incorporating pillar[5]arenes (P5-CMPs) with surface areas up to 400 m(2) g(-1) via Pd-catalyzed Sonogashira Hagihara cross-coupling reaction of triflate functionalized pillar[5]arene with 1,4-diethynylbenzene and 4,4'-diethyny1-1,1'-biphenyl linkers. In an effort to transfer intrinsic properties of pillar[5]arene, that is its ability to form strong host guest complexes with linear hydrocarbons in solution, into the solid-state, we investigated the affinity of P5-CMPs toward propane gas. Unlike previously reported porous solids, which showed isosteric heats of adsorption (Q(st)) for propane in the range of 32.9-36.9 kJ mol(-1) at zero coverage and increasing Q(st) with rising loading due to intermolecular interactions between propane molecules, we observed very high Q(st) values up to 53 kJ mol(-1) at zero coverage, which gradually decreased to similar to 35 kJ mol(-1) with increasing loadings. This observation indicates strong supramolecular host-guest complexation between propane and pillar[S]arene via multiple C-H/pi interactions, i.e., "macrocyclic effect" arising from the ideal size match of kinetic diameter of propane to the cavity of pillar[S]arene. This approach also allowed us to introduce thermodynamic selectivity for the separation of saturated hydrocarbons with low polarizability. High affinity of P5-CMPs for propane facilitated its efficient breakthrough separation from a simulated natural gas mixture (methane:propane, 9:1) at 298 K | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Pillar[5]arene Based Conjugated Microporous Polymers for Propane/Methane Separation through Host-Guest Complexation | - |
dc.type | Article | - |
dc.identifier.wosid | 000378973100043 | - |
dc.identifier.scopusid | 2-s2.0-84976897208 | - |
dc.type.rims | ART | - |
dc.citation.volume | 28 | - |
dc.citation.issue | 12 | - |
dc.citation.beginningpage | 4460 | - |
dc.citation.endingpage | 4466 | - |
dc.citation.publicationname | CHEMISTRY OF MATERIALS | - |
dc.identifier.doi | 10.1021/acs.chemmater.6b01667 | - |
dc.contributor.localauthor | Coskun, Ali | - |
dc.contributor.nonIdAuthor | Talapaneni, Siddulu Naidu | - |
dc.contributor.nonIdAuthor | Barin, Gokhan | - |
dc.contributor.nonIdAuthor | Buyukcakir, Onur | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | METAL-ORGANIC FRAMEWORKS | - |
dc.subject.keywordPlus | GAS SORPTION PROPERTIES | - |
dc.subject.keywordPlus | SELECTIVE ADSORPTION | - |
dc.subject.keywordPlus | SUPRAMOLECULAR POLYMERS | - |
dc.subject.keywordPlus | TRANSMEMBRANE CHANNELS | - |
dc.subject.keywordPlus | KINETIC SEPARATION | - |
dc.subject.keywordPlus | PROPANE | - |
dc.subject.keywordPlus | ETHYLENE | - |
dc.subject.keywordPlus | NETWORKS | - |
dc.subject.keywordPlus | ETHANE | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.