DC Field | Value | Language |
---|---|---|
dc.contributor.author | Song, Hyunjoon | ko |
dc.contributor.author | Lee, K | ko |
dc.contributor.author | Choi, MG | ko |
dc.contributor.author | Park, Joon Taik | ko |
dc.date.accessioned | 2010-12-24T02:29:49Z | - |
dc.date.available | 2010-12-24T02:29:49Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2002-04 | - |
dc.identifier.citation | ORGANOMETALLICS, v.21, no.9, pp.1756 - 1758 | - |
dc.identifier.issn | 0276-7333 | - |
dc.identifier.uri | http://hdl.handle.net/10203/21222 | - |
dc.description.abstract | A new 1,2-sigma-type C-60 compound, OS3(CO)(7)(CNR)(mu(3)-CNR)(PPh3)(mu(3)-eta(1):eta(1):eta(2)-C-60) (2; R = CH2Ph), is formed from Os-3(CO)(8)(CNR)(mu(3)-CNR)(mu(3)-eta(1):eta(2):eta(1)-C-60) (1) upon substitution of CO with PPh3 on a triosmium cluster framework. Compounds 1 and 2 are reversibly interconvertible. Further reaction of 2 with PPh3 results in a pi-type C-60 complex, Os-3(CO)(6)(CNR)(mu(3)-CNCH2C6H4)(PPh3)(mu-PPh2)(mu-eta(2):eta(2)-C-60) (3), with an Os-Os bond cleavage. | - |
dc.description.sponsorship | This work was supported by the National Research Laboratory (NRL) Program of the Korean Ministry of Science & Technology (MOST) and the Korea Science Engineering Foundation (Project No.1999-1-122-001-5). | en |
dc.language | English | - |
dc.language.iso | en_US | en |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | TRIOSMIUM CLUSTER COMPLEXES | - |
dc.subject | STRUCTURAL CHARACTERIZATION | - |
dc.subject | C-60 | - |
dc.subject | MU(3)-ETA(2),ETA(2),ETA(2)-C-60 | - |
dc.subject | PENTARUTHENIUM | - |
dc.subject | DERIVATIVES | - |
dc.title | [60]fullerene as a versatile four-electron donor ligand | - |
dc.type | Article | - |
dc.identifier.wosid | 000175369600004 | - |
dc.identifier.scopusid | 2-s2.0-0000628319 | - |
dc.type.rims | ART | - |
dc.citation.volume | 21 | - |
dc.citation.issue | 9 | - |
dc.citation.beginningpage | 1756 | - |
dc.citation.endingpage | 1758 | - |
dc.citation.publicationname | ORGANOMETALLICS | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Song, Hyunjoon | - |
dc.contributor.localauthor | Park, Joon Taik | - |
dc.contributor.nonIdAuthor | Lee, K | - |
dc.contributor.nonIdAuthor | Choi, MG | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | TRIOSMIUM CLUSTER COMPLEXES | - |
dc.subject.keywordPlus | STRUCTURAL CHARACTERIZATION | - |
dc.subject.keywordPlus | C-60 | - |
dc.subject.keywordPlus | MU(3)-ETA(2),ETA(2),ETA(2)-C-60 | - |
dc.subject.keywordPlus | PENTARUTHENIUM | - |
dc.subject.keywordPlus | DERIVATIVES | - |
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