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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

A Direct Access to 7-Aminoindoles via Iridium-Catalyzed Mild C-H Amidation of N-Pivaloylindoles with Organic Azides

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dc.contributor.authorKim, Youyoungko
dc.contributor.authorPark, Juhyeonko
dc.contributor.authorChang, Sukbokko
dc.date.accessioned2016-07-04T06:00:22Z-
dc.date.available2016-07-04T06:00:22Z-
dc.date.created2016-05-16-
dc.date.created2016-05-16-
dc.date.issued2016-04-
dc.identifier.citationORGANIC LETTERS, v.18, no.8, pp.1892 - 1895-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10203/209110-
dc.description.abstractIr(III)-catalyzed regioselective direct C-7 amidation of indoles in reaction with organic azides has been developed. While its efficiency was varied by the choice of N-directing groups, N-pivaloylindoles were most effective in undergoing the desired amidation at room temperature over a broad range of substrates. The reaction was scalable, and deprotection of the chelation group was also facile-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectBOND-FORMING REACTIONS-
dc.subjectSULFONYL AZIDES-
dc.subjectARYL AZIDES-
dc.subjectNITROGEN-SOURCE-
dc.subjectACTIVATION-
dc.subjectINDOLES-
dc.subjectAMINATION-
dc.subjectFUNCTIONALIZATION-
dc.subjectARYLATION-
dc.subjectHETEROCYCLES-
dc.titleA Direct Access to 7-Aminoindoles via Iridium-Catalyzed Mild C-H Amidation of N-Pivaloylindoles with Organic Azides-
dc.typeArticle-
dc.identifier.wosid000374436800046-
dc.identifier.scopusid2-s2.0-84966292059-
dc.type.rimsART-
dc.citation.volume18-
dc.citation.issue8-
dc.citation.beginningpage1892-
dc.citation.endingpage1895-
dc.citation.publicationnameORGANIC LETTERS-
dc.identifier.doi10.1021/acs.orglett.6b00662-
dc.contributor.localauthorChang, Sukbok-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordPlusBOND-FORMING REACTIONS-
dc.subject.keywordPlusSULFONYL AZIDES-
dc.subject.keywordPlusARYL AZIDES-
dc.subject.keywordPlusNITROGEN-SOURCE-
dc.subject.keywordPlusACTIVATION-
dc.subject.keywordPlusINDOLES-
dc.subject.keywordPlusAMINATION-
dc.subject.keywordPlusFUNCTIONALIZATION-
dc.subject.keywordPlusARYLATION-
dc.subject.keywordPlusHETEROCYCLES-
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CH-Journal Papers(저널논문)
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