DC Field | Value | Language |
---|---|---|
dc.contributor.author | Smith, Kyle T. | ko |
dc.contributor.author | Berritt, Simon | ko |
dc.contributor.author | Gonzalez-Moreiras, Mariano | ko |
dc.contributor.author | Ahn, Seihwan | ko |
dc.contributor.author | Smith, Milton R., III | ko |
dc.contributor.author | Baik, Mu-Hyun | ko |
dc.contributor.author | Mindiola, Daniel J. | ko |
dc.date.accessioned | 2016-06-30T00:34:30Z | - |
dc.date.available | 2016-06-30T00:34:30Z | - |
dc.date.created | 2016-04-19 | - |
dc.date.created | 2016-04-19 | - |
dc.date.issued | 2016-03 | - |
dc.identifier.citation | SCIENCE, v.351, no.6280, pp.1424 - 1427 | - |
dc.identifier.issn | 0036-8075 | - |
dc.identifier.uri | http://hdl.handle.net/10203/208659 | - |
dc.description.abstract | Despite steady progress in catalytic methods for the borylation of hydrocarbons, methane has not yet been subject to this transformation. Here we report the iridium-catalyzed borylation of methane using bis(pinacolborane) in cyclohexane solvent. Initially, trace amounts of borylated products were detected with phenanthroline-coordinated Ir complexes. A combination of experimental high-pressure and high-throughput screening, and computational mechanism discovery techniques helped to rationalize the foundation of the catalysis and identify improved phosphine-coordinated catalytic complexes. Optimized conditions of 150 degrees C and 3500-kilopascal pressure led to yields as high as similar to 52%, turnover numbers of 100, and improved chemoselectivity for monoborylated versus diborylated methane | - |
dc.language | English | - |
dc.publisher | AMER ASSOC ADVANCEMENT SCIENCE | - |
dc.subject | C-H BONDS | - |
dc.subject | ORGANOMETALLIC CHEMISTRY | - |
dc.subject | ACETIC-ACID | - |
dc.subject | ACTIVATION | - |
dc.subject | COMPLEXES | - |
dc.subject | FUNCTIONALIZATION | - |
dc.subject | CONVERSION | - |
dc.subject | CH4 | - |
dc.subject | HYDROCARBONS | - |
dc.subject | FRONTIER | - |
dc.title | Catalytic borylation of methane | - |
dc.type | Article | - |
dc.identifier.wosid | 000372756200041 | - |
dc.identifier.scopusid | 2-s2.0-84962210343 | - |
dc.type.rims | ART | - |
dc.citation.volume | 351 | - |
dc.citation.issue | 6280 | - |
dc.citation.beginningpage | 1424 | - |
dc.citation.endingpage | 1427 | - |
dc.citation.publicationname | SCIENCE | - |
dc.identifier.doi | 10.1126/science.aad9730 | - |
dc.contributor.localauthor | Baik, Mu-Hyun | - |
dc.contributor.nonIdAuthor | Smith, Kyle T. | - |
dc.contributor.nonIdAuthor | Berritt, Simon | - |
dc.contributor.nonIdAuthor | Gonzalez-Moreiras, Mariano | - |
dc.contributor.nonIdAuthor | Smith, Milton R., III | - |
dc.contributor.nonIdAuthor | Mindiola, Daniel J. | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | C-H BONDS | - |
dc.subject.keywordPlus | ORGANOMETALLIC CHEMISTRY | - |
dc.subject.keywordPlus | ACETIC-ACID | - |
dc.subject.keywordPlus | ACTIVATION | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | FUNCTIONALIZATION | - |
dc.subject.keywordPlus | CONVERSION | - |
dc.subject.keywordPlus | CH4 | - |
dc.subject.keywordPlus | HYDROCARBONS | - |
dc.subject.keywordPlus | FRONTIER | - |
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