DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Hyunwoo | ko |
dc.contributor.author | Chang, Sukbok | ko |
dc.date.accessioned | 2016-05-16T08:52:51Z | - |
dc.date.available | 2016-05-16T08:52:51Z | - |
dc.date.created | 2015-12-10 | - |
dc.date.created | 2015-12-10 | - |
dc.date.issued | 2015-11 | - |
dc.identifier.citation | ACS Catalysis, v.5, no.11, pp.6665 - 6669 | - |
dc.identifier.issn | 2155-5435 | - |
dc.identifier.uri | http://hdl.handle.net/10203/207499 | - |
dc.description.abstract | Described herein is the development of Cp*Ir-(III)-catalyzed direct arene C-H amination using alkylamines as an amino source. This C-N bond formation showcases a notable example of cross-dehydrogenative coupling to install an amino functionality at the ortho-position of benzamide substrates. Mechanistic studies including the isolation of an amine-bound iridacyclic intermediate along with a set of chemical oxidations demonstrated the Ir-catalyzed inner-sphere C-H amination with primary alkylamines for the first time. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | TRANSITION-METAL-COMPLEXES | - |
dc.subject | CARBON-NITROGEN BONDS | - |
dc.subject | ROOM-TEMPERATURE | - |
dc.subject | ARYL HALIDES | - |
dc.subject | INTERMOLECULAR AMIDATION | - |
dc.subject | COUPLING REACTIONS | - |
dc.subject | SODIUM PERSULFATE | - |
dc.subject | ORTHO-ARYLATION | - |
dc.subject | N-CHLOROAMINES | - |
dc.subject | SIMPLE ARENES | - |
dc.title | Iridium-Catalyzed Direct C-H Amination with Alkylamines: Facile Oxidative Insertion of Amino Group into Iridacycle | - |
dc.type | Article | - |
dc.identifier.wosid | 000364441300052 | - |
dc.identifier.scopusid | 2-s2.0-84946831548 | - |
dc.type.rims | ART | - |
dc.citation.volume | 5 | - |
dc.citation.issue | 11 | - |
dc.citation.beginningpage | 6665 | - |
dc.citation.endingpage | 6669 | - |
dc.citation.publicationname | ACS Catalysis | - |
dc.identifier.doi | 10.1021/acscatal.5b02165 | - |
dc.contributor.localauthor | Chang, Sukbok | - |
dc.contributor.nonIdAuthor | Kim, Hyunwoo | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | iridium catalysis | - |
dc.subject.keywordAuthor | C-H amination | - |
dc.subject.keywordAuthor | alkylamines | - |
dc.subject.keywordAuthor | oxidative coupling | - |
dc.subject.keywordAuthor | cross-dehydrogenative coupling | - |
dc.subject.keywordPlus | TRANSITION-METAL-COMPLEXES | - |
dc.subject.keywordPlus | CARBON-NITROGEN BONDS | - |
dc.subject.keywordPlus | ROOM-TEMPERATURE | - |
dc.subject.keywordPlus | ARYL HALIDES | - |
dc.subject.keywordPlus | INTERMOLECULAR AMIDATION | - |
dc.subject.keywordPlus | COUPLING REACTIONS | - |
dc.subject.keywordPlus | SODIUM PERSULFATE | - |
dc.subject.keywordPlus | ORTHO-ARYLATION | - |
dc.subject.keywordPlus | N-CHLOROAMINES | - |
dc.subject.keywordPlus | SIMPLE ARENES | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.