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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Catalyst Controlled Divergent C4/C8 Site-Selective C-H Arylation of Isoquinolones

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dc.contributor.authorLee, Soyoungko
dc.contributor.authorMah, Shinmeeko
dc.contributor.authorHong, Sungwooko
dc.date.accessioned2016-04-15T03:06:37Z-
dc.date.available2016-04-15T03:06:37Z-
dc.date.created2015-09-07-
dc.date.created2015-09-07-
dc.date.issued2015-08-
dc.identifier.citationORGANIC LETTERS, v.17, no.15, pp.3864 - 3867-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10203/203969-
dc.description.abstractThe catalyst-controlled C4/C8 site-selective C-H arylation of isoquinolones using aryliodonium salts as the coupling partners was developed. The C4-selective arylation was successfully achieved via an electrophilic palladation pathway. A completely different selectivity pattern was observed using an Ir(III) catalytic system, which resulted in C-C bond formation exclusively at the C8 position. The isoquinolone scaffold can be conveniently equipped with various aryl substituents at either the C4 or C8 position.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectDIARYLIODONIUM SALTS-
dc.subjectBOND ACTIVATION-
dc.subjectMILD CONDITIONS-
dc.subjectACID-DERIVATIVES-
dc.subjectALKYNES-
dc.subjectOLEFINATION-
dc.subjectANNULATION-
dc.subjectROUTE-
dc.subjectFUNCTIONALIZATION-
dc.subjectC(SP(2))-H-
dc.titleCatalyst Controlled Divergent C4/C8 Site-Selective C-H Arylation of Isoquinolones-
dc.typeArticle-
dc.identifier.wosid000359393800057-
dc.identifier.scopusid2-s2.0-84938893467-
dc.type.rimsART-
dc.citation.volume17-
dc.citation.issue15-
dc.citation.beginningpage3864-
dc.citation.endingpage3867-
dc.citation.publicationnameORGANIC LETTERS-
dc.identifier.doi10.1021/acs.orglett.5b01840-
dc.contributor.localauthorHong, Sungwoo-
dc.type.journalArticleArticle-
dc.subject.keywordPlusDIARYLIODONIUM SALTS-
dc.subject.keywordPlusBOND ACTIVATION-
dc.subject.keywordPlusMILD CONDITIONS-
dc.subject.keywordPlusACID-DERIVATIVES-
dc.subject.keywordPlusALKYNES-
dc.subject.keywordPlusOLEFINATION-
dc.subject.keywordPlusANNULATION-
dc.subject.keywordPlusROUTE-
dc.subject.keywordPlusFUNCTIONALIZATION-
dc.subject.keywordPlusC(SP(2))-H-
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