DC Field | Value | Language |
---|---|---|
dc.contributor.author | Thompson, Rick | ko |
dc.contributor.author | Tran, Ba L. | ko |
dc.contributor.author | Ghosh, Soumya | ko |
dc.contributor.author | Chen, Chun-Hsing | ko |
dc.contributor.author | Pink, Maren | ko |
dc.contributor.author | Gao, Xinfeng | ko |
dc.contributor.author | Carroll, Patrick J. | ko |
dc.contributor.author | Baik, Mu-Hyun | ko |
dc.contributor.author | Mindiola, Daniel J. | ko |
dc.date.accessioned | 2016-04-12T07:25:56Z | - |
dc.date.available | 2016-04-12T07:25:56Z | - |
dc.date.created | 2015-09-11 | - |
dc.date.created | 2015-09-11 | - |
dc.date.issued | 2015-03 | - |
dc.identifier.citation | INORGANIC CHEMISTRY, v.54, no.6, pp.3068 - 3077 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | http://hdl.handle.net/10203/203285 | - |
dc.description.abstract | In this study we enumerate the reactivity for two molecular vanadium nitrido complexes of anatnac)V equivalent to N(X)] formulation [nacnac = (Ar)NC(Me)CHC(Me)(Ar)(-), Ar = 2,6-(CHMe2)(2)C6H3); X- = OAr (1) and N(4-Me-C6H4)(2) (Ntolyl(2)) (2)]. Density functional theory calculations and reactivity studies indicate the nitride motif to have nudeophilic character, but where the nitrogen atom can serve as a conduit for electron transfer, thus allowing the reduction of the vanadium(V) metal ion with concurrent oxidation of the incoming substrate. Silane, H2SiPh2, readily converts the nitride ligand in 1 into a primary Silyl amide functionality with concomitant two-electron reduction at the vanadium center to form the complex [(nacnac)V{N(H)SiHPh2}(OAr)] (3). Likewise, addition of the B-H bond in pinacolborane to the nitride moiety in 2 results in formation of the boryl amide complex [(nacnac)V{N(H)B(pinacol)}(Ntolyl(2))] (4). In addition to spectroscopic data, complexes 3 and 4 were also elucidated structurally by single-crystal X-ray diffraction analysis. One-electron reduction of 1 With 0.5% Na/Hg on a preparative scale allowed for the isolation and structural determination of an asymmetric bimolecular nitride radical anion complex having formula [Na](2)[(nacnac)V(N)(OAr)](2) (5), in addition to room-temperature solution X-band electron paramagnetic resonance spectroscopic studies. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | TRANSITION-METAL-COMPLEXES | - |
dc.subject | EFFECTIVE CORE POTENTIALS | - |
dc.subject | DINITROGEN CLEAVAGE | - |
dc.subject | MOLECULAR CALCULATIONS | - |
dc.subject | ELECTRONIC-STRUCTURE | - |
dc.subject | CRYSTAL-STRUCTURES | - |
dc.subject | ALKYNE METATHESIS | - |
dc.subject | TERMINAL NITRIDO | - |
dc.subject | CARBON BONDS | - |
dc.subject | SOLID-STATE | - |
dc.title | Addition of Si-H and B-H Bonds and Redox Reactivity Involving Low-Coordinate Nitrido-Vanadium Complexes | - |
dc.type | Article | - |
dc.identifier.wosid | 000351325200063 | - |
dc.identifier.scopusid | 2-s2.0-84924872391 | - |
dc.type.rims | ART | - |
dc.citation.volume | 54 | - |
dc.citation.issue | 6 | - |
dc.citation.beginningpage | 3068 | - |
dc.citation.endingpage | 3077 | - |
dc.citation.publicationname | INORGANIC CHEMISTRY | - |
dc.identifier.doi | 10.1021/acs.inorgchem.5b00302 | - |
dc.contributor.localauthor | Baik, Mu-Hyun | - |
dc.contributor.nonIdAuthor | Thompson, Rick | - |
dc.contributor.nonIdAuthor | Tran, Ba L. | - |
dc.contributor.nonIdAuthor | Ghosh, Soumya | - |
dc.contributor.nonIdAuthor | Chen, Chun-Hsing | - |
dc.contributor.nonIdAuthor | Pink, Maren | - |
dc.contributor.nonIdAuthor | Gao, Xinfeng | - |
dc.contributor.nonIdAuthor | Carroll, Patrick J. | - |
dc.contributor.nonIdAuthor | Mindiola, Daniel J. | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | EFFECTIVE CORE POTENTIALS | - |
dc.subject.keywordPlus | TRANSITION-METAL-COMPLEXES | - |
dc.subject.keywordPlus | MOLECULAR CALCULATIONS | - |
dc.subject.keywordPlus | DINITROGEN CLEAVAGE | - |
dc.subject.keywordPlus | ELECTRONIC-STRUCTURE | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURES | - |
dc.subject.keywordPlus | ALKYNE METATHESIS | - |
dc.subject.keywordPlus | TERMINAL NITRIDO | - |
dc.subject.keywordPlus | CARBON BONDS | - |
dc.subject.keywordPlus | SOLID-STATE | - |
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