Polymer Brushes via Controlled, Surface-Initiated Atom Transfer Radical Polymerization (ATRP) from Graphene Oxide

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dc.contributor.authorLee, Sun-Hwako
dc.contributor.authorDreyer, Daniel R.ko
dc.contributor.authorAn, Jin-Hoko
dc.contributor.authorVelamakanni, Arunako
dc.contributor.authorPiner, Richard D.ko
dc.contributor.authorPark, Sung-Jinko
dc.contributor.authorZhu, Yan-Wuko
dc.contributor.authorKim, Sang-Oukko
dc.contributor.authorBielawski, Christopher W.ko
dc.contributor.authorRuoff, Rodney S.ko
dc.date.accessioned2010-11-23-
dc.date.available2010-11-23-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2010-02-
dc.identifier.citationMACROMOLECULAR RAPID COMMUNICATIONS, v.31, no.3, pp.281 - 288-
dc.identifier.issn1022-1336-
dc.identifier.urihttp://hdl.handle.net/10203/20240-
dc.description.abstractA method for growing polymers directly from the surface of graphene oxide is demonstrated. The technique involves the covalent attachment of an initiator followed by the polymerization of styrene, methyl methacrylate, or butyl acrylate using atom transfer radical polymerization (ATRP). The resulting materials were characterized using a range of techniques and were found to significantly improve the solubility properties of graphene oxide. The surface-grown polymers were saponified from the surface and also characterized. Based on these results, the ATRP reactions were determined to proceed in a controlled manner and were found to leave the structure of the graphene oxide largely intact.-
dc.description.sponsorshipThis research was supported by the second stage of the Brain Korea 21 project, the National Research Laboratory Program (R0A-2008-000-20057-0), funded by the Korean Government (MEST), the National Science Foundation (DMR-0907324), and the Welch Foundation (F-1621).en
dc.languageEnglish-
dc.language.isoen_USen
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectGRAPHITE OXIDE-
dc.subjectSHEETS-
dc.subjectNANOCOMPOSITES-
dc.subjectDISPERSION-
dc.subjectDENSITY-
dc.titlePolymer Brushes via Controlled, Surface-Initiated Atom Transfer Radical Polymerization (ATRP) from Graphene Oxide-
dc.typeArticle-
dc.identifier.wosid000274936500006-
dc.identifier.scopusid2-s2.0-75749112101-
dc.type.rimsART-
dc.citation.volume31-
dc.citation.issue3-
dc.citation.beginningpage281-
dc.citation.endingpage288-
dc.citation.publicationnameMACROMOLECULAR RAPID COMMUNICATIONS-
dc.identifier.doi10.1002/marc.200900641-
dc.embargo.liftdate9999-12-31-
dc.embargo.terms9999-12-31-
dc.contributor.localauthorKim, Sang-Ouk-
dc.contributor.nonIdAuthorDreyer, Daniel R.-
dc.contributor.nonIdAuthorAn, Jin-Ho-
dc.contributor.nonIdAuthorVelamakanni, Aruna-
dc.contributor.nonIdAuthorPiner, Richard D.-
dc.contributor.nonIdAuthorPark, Sung-Jin-
dc.contributor.nonIdAuthorZhu, Yan-Wu-
dc.contributor.nonIdAuthorBielawski, Christopher W.-
dc.contributor.nonIdAuthorRuoff, Rodney S.-
dc.type.journalArticleArticle-
dc.subject.keywordAuthoratom transfer radical polymerization (ATRP)-
dc.subject.keywordAuthorgraphene-
dc.subject.keywordAuthorgraphene oxide-
dc.subject.keywordAuthorsurfaces-
dc.subject.keywordPlusGRAPHITE OXIDE-
dc.subject.keywordPlusSHEETS-
dc.subject.keywordPlusNANOCOMPOSITES-
dc.subject.keywordPlusDISPERSION-
dc.subject.keywordPlusDENSITY-
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