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College of Engineering(공과대학)Dept. of Materials Science and Engineering(신소재공학과)MS-Journal Papers(저널논문)

Synthesis and electrochemical properties of layered LiNi2/3Sb1/3O2

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dc.contributor.authorMa XH (Ma, Xiaohua)ko
dc.contributor.authorKang KS (Kang, Kisuk)ko
dc.contributor.authorCeder G (Ceder, Gerbrand)ko
dc.contributor.authorMeng YS (Meng, Ying Shirley)ko
dc.date.accessioned2010-11-18T07:37:50Z-
dc.date.available2010-11-18T07:37:50Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2007-11-
dc.identifier.citationJOURNAL OF POWER SOURCES, v.173, no.1, pp.550 - 555-
dc.identifier.issn0378-7753-
dc.identifier.urihttp://hdl.handle.net/10203/20125-
dc.description.abstractLiNi2/3Sb1/3O2 has been prepared by ion-exchange from NaNi2/3Sb1/3O2. Powder X-ray diffraction (XRD) and single crystal electron diffraction by transmission electron microscopy (TEM) of the material indicate that it is isostructural with alpha-NaFeO2. Electrochemical test shows that the reversible capacity for Li intercalation and deintercalation drops rapidly with the number of times cycled. Both experimental evidences and first principles calculations point to the migration of nickel as the reason for the poor capacity retention. (C) 2007 Published by Elsevier B.V.-
dc.description.sponsorshipThis work was supported by the Assistant Secretary for Energy Efficiency, Office of FreedomCAR and Vehicle Technologies of the US Department of Energy under contract No.DE-AC02-05CH11231, via subcontract No. PO 6806960. We also acknowledge the support by the Center for Materials Science and Engineering atMITunder contract No. DMR-0213282. Valuable discussion with Prof. C.P. Grey is acknowledged. X.H. Ma would like to thank Y. Hinuma and B. Kang for their fruitful discussions.en
dc.languageEnglish-
dc.language.isoen_USen
dc.publisherELSEVIER SCIENCE BV-
dc.subjectRECHARGEABLE LITHIUM BATTERIES-
dc.subjectCATHODE MATERIALS-
dc.subjectION BATTERIES-
dc.subjectOXIDES-
dc.subjectLINI0.5MN0.5O2-
dc.subjectDIFFUSION-
dc.subjectLICOO2-
dc.titleSynthesis and electrochemical properties of layered LiNi2/3Sb1/3O2-
dc.typeArticle-
dc.identifier.wosid000250995200062-
dc.identifier.scopusid2-s2.0-34848927864-
dc.type.rimsART-
dc.citation.volume173-
dc.citation.issue1-
dc.citation.beginningpage550-
dc.citation.endingpage555-
dc.citation.publicationnameJOURNAL OF POWER SOURCES-
dc.identifier.doi10.1016/j.jpowsour.2007.07.033-
dc.embargo.liftdate9999-12-31-
dc.embargo.terms9999-12-31-
dc.contributor.localauthorKang KS (Kang, Kisuk)-
dc.contributor.nonIdAuthorMa XH (Ma, Xiaohua)-
dc.contributor.nonIdAuthorCeder G (Ceder, Gerbrand)-
dc.contributor.nonIdAuthorMeng YS (Meng, Ying Shirley)-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorlithium ion battery-
dc.subject.keywordAuthorion-exchange-
dc.subject.keywordAuthorantimony-
dc.subject.keywordAuthorlayered oxide-
dc.subject.keywordPlusRECHARGEABLE LITHIUM BATTERIES-
dc.subject.keywordPlusCATHODE MATERIALS-
dc.subject.keywordPlusION BATTERIES-
dc.subject.keywordPlusOXIDES-
dc.subject.keywordPlusLINI0.5MN0.5O2-
dc.subject.keywordPlusDIFFUSION-
dc.subject.keywordPlusLICOO2-
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