DC Field | Value | Language |
---|---|---|
dc.contributor.author | Patel, Hasmukh A. | ko |
dc.contributor.author | Ko, Dongah | ko |
dc.contributor.author | Yavuz, Cafer T. | ko |
dc.date.accessioned | 2015-11-20T09:09:15Z | - |
dc.date.available | 2015-11-20T09:09:15Z | - |
dc.date.created | 2015-01-20 | - |
dc.date.created | 2015-01-20 | - |
dc.date.issued | 2014-12 | - |
dc.identifier.citation | CHEMISTRY OF MATERIALS, v.26, no.23, pp.6729 - 6733 | - |
dc.identifier.issn | 0897-4756 | - |
dc.identifier.uri | http://hdl.handle.net/10203/201046 | - |
dc.description.abstract | The pursuit of synthetic routes for design and preparation of nanoporous polymeric networks with inherent permanent microporosity and functionality through bottom-up methodologies remains a driving force in developing CO2-philic materials. We report nanoporous, processable, benzoxazole-linked covalent organic polymers (Box-COPs) that show exceptional thermal stability up to 576 degrees C. Box-COPs can be formed into films thanks to the silylation that is used to guide polymeric network formation. Surface areas of up to 606 m(2) g(-1) and narrow pore sizes of 4.36 angstrom were observed with a CO2 uptake capacity of 139.6 mg g(-1) at 273 K and 1 bar. Box-COPs were stable in boiling water for a week without deteriorating CO2 capture capacity. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | COVALENT ORGANIC FRAMEWORKS | - |
dc.subject | HIGH-SURFACE-AREA | - |
dc.subject | CO2 CAPTURE | - |
dc.subject | GAS-STORAGE | - |
dc.subject | POLYMER NETWORKS | - |
dc.subject | LINKED POLYMERS | - |
dc.subject | ADSORPTION | - |
dc.subject | BASE | - |
dc.subject | H-2 | - |
dc.title | Nanoporous Benzoxazole Networks by Silylated Monomers, Their Exceptional Thermal Stability, and Carbon Dioxide Capture Capacity | - |
dc.type | Article | - |
dc.identifier.wosid | 000346326300009 | - |
dc.identifier.scopusid | 2-s2.0-84916624752 | - |
dc.type.rims | ART | - |
dc.citation.volume | 26 | - |
dc.citation.issue | 23 | - |
dc.citation.beginningpage | 6729 | - |
dc.citation.endingpage | 6733 | - |
dc.citation.publicationname | CHEMISTRY OF MATERIALS | - |
dc.identifier.doi | 10.1021/cm503627p | - |
dc.contributor.localauthor | Yavuz, Cafer T. | - |
dc.contributor.nonIdAuthor | Ko, Dongah | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | COVALENT ORGANIC FRAMEWORKS | - |
dc.subject.keywordPlus | HIGH-SURFACE-AREA | - |
dc.subject.keywordPlus | CO2 CAPTURE | - |
dc.subject.keywordPlus | GAS-STORAGE | - |
dc.subject.keywordPlus | POLYMER NETWORKS | - |
dc.subject.keywordPlus | LINKED POLYMERS | - |
dc.subject.keywordPlus | ADSORPTION | - |
dc.subject.keywordPlus | BASE | - |
dc.subject.keywordPlus | H-2 | - |
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