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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Direct C-H Amidation of Benzoic Acids to Introduce meta- and para-Amino Groups by Tandem Decarboxylation

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dc.contributor.authorLee, Dong Gunko
dc.contributor.authorChang, Suk-Bokko
dc.date.accessioned2015-11-20T09:05:49Z-
dc.date.available2015-11-20T09:05:49Z-
dc.date.created2015-05-12-
dc.date.created2015-05-12-
dc.date.issued2015-03-
dc.identifier.citationCHEMISTRY-A EUROPEAN JOURNAL, v.21, no.14, pp.5364 - 5368-
dc.identifier.issn0947-6539-
dc.identifier.urihttp://hdl.handle.net/10203/201003-
dc.description.abstractThe Ir-catalyzed mild C-H amidation of benzoic acids with sulfonyl azides was developed to give reactions with high efficiency and functional-group compatibility. Subsequent protodecarboxylation of ortho-amidated benzoic acid products afforded meta-or para-substituted (N-sulfonyl) aniline derivatives, the latter being inaccessible by other C-H functionalization approaches. The decarboxylation step was compatible with the amidation conditions, enabling a convenient one-pot, two-step process.-
dc.languageEnglish-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectAROMATIC CARBOXYLIC-ACIDS-
dc.subjectCOPPER-CATALYZED DECARBOXYLATION-
dc.subjectCONVENIENT SYNTHESIS-
dc.subjectANTHRANILIC ACIDS-
dc.subjectROOM-TEMPERATURE-
dc.subjectORTHO AMINATION-
dc.subjectN-CHLOROAMINES-
dc.subjectARYL HALIDES-
dc.subjectPROTODECARBOXYLATION-
dc.subjectFUNCTIONALIZATION-
dc.titleDirect C-H Amidation of Benzoic Acids to Introduce meta- and para-Amino Groups by Tandem Decarboxylation-
dc.typeArticle-
dc.identifier.wosid000352504500015-
dc.identifier.scopusid2-s2.0-84925100417-
dc.type.rimsART-
dc.citation.volume21-
dc.citation.issue14-
dc.citation.beginningpage5364-
dc.citation.endingpage5368-
dc.citation.publicationnameCHEMISTRY-A EUROPEAN JOURNAL-
dc.identifier.doi10.1002/chem.201500331-
dc.contributor.localauthorChang, Suk-Bok-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorC-H amidation-
dc.subject.keywordAuthordecarboxylation-
dc.subject.keywordAuthormeta- and para-substituted anilines-
dc.subject.keywordAuthortandem processes-
dc.subject.keywordAuthortraceless directing groups-
dc.subject.keywordPlusAROMATIC CARBOXYLIC-ACIDS-
dc.subject.keywordPlusCOPPER-CATALYZED DECARBOXYLATION-
dc.subject.keywordPlusCONVENIENT SYNTHESIS-
dc.subject.keywordPlusANTHRANILIC ACIDS-
dc.subject.keywordPlusROOM-TEMPERATURE-
dc.subject.keywordPlusORTHO AMINATION-
dc.subject.keywordPlusN-CHLOROAMINES-
dc.subject.keywordPlusARYL HALIDES-
dc.subject.keywordPlusPROTODECARBOXYLATION-
dc.subject.keywordPlusFUNCTIONALIZATION-
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CH-Journal Papers(저널논문)
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