DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Yeong-Eun | ko |
dc.contributor.author | Oh, Seohee | ko |
dc.contributor.author | Kim, Seji | ko |
dc.contributor.author | Kim, Onnuri | ko |
dc.contributor.author | Kim, Jin | ko |
dc.contributor.author | Han, Sang-Woo | ko |
dc.contributor.author | Lee, Yunho | ko |
dc.date.accessioned | 2015-11-20T09:05:28Z | - |
dc.date.available | 2015-11-20T09:05:28Z | - |
dc.date.created | 2015-04-09 | - |
dc.date.created | 2015-04-09 | - |
dc.date.created | 2015-04-09 | - |
dc.date.issued | 2015-04 | - |
dc.identifier.citation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.137, no.13, pp.4280 - 4283 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/10203/200998 | - |
dc.description.abstract | Reversible transformations are observed between a phosphide-nickel(II) alkoxide and a phosphinite-nickel(0) species via a P-O bond formation coupled with a 2-e(-) redox change at the nickel center. In the forward reaction, the nickel(0) dinitrogen species ((PPP)-P-OMe)Ni(N-2) (2) and {((PPP)-P-OMe)Ni}(2)(mu-N-2) (3) were formed from the reaction of (PPP)NiCl (1) with a methoxy anion. In the backward reaction, a (PPP)Ni(II) moiety was regenerated from the CO2 reaction of 3 with the concomitant formation of a methyl carbonate ligand in (PPP)Ni(OCOOMe) (7). Thus, unanticipated metal-ligand cooperation involving a phosphide based ligand is reported. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | REDOX-ACTIVE LIGANDS | - |
dc.subject | H OXIDATIVE ADDITION | - |
dc.subject | CARBON-DIOXIDE | - |
dc.subject | ALKOXIDE COMPLEXES | - |
dc.subject | BOND ACTIVATION | - |
dc.subject | PINCER LIGANDS | - |
dc.subject | CO2 FIXATION | - |
dc.subject | CATALYSIS | - |
dc.subject | REACTIVITY | - |
dc.subject | COMPOUND | - |
dc.title | Phosphinite-Ni(0) Mediated Formation of a Phosphide-Ni(II)-OCOOMe Species via Uncommon Metal-Ligand Cooperation | - |
dc.type | Article | - |
dc.identifier.wosid | 000352752000002 | - |
dc.identifier.scopusid | 2-s2.0-84926431706 | - |
dc.type.rims | ART | - |
dc.citation.volume | 137 | - |
dc.citation.issue | 13 | - |
dc.citation.beginningpage | 4280 | - |
dc.citation.endingpage | 4283 | - |
dc.citation.publicationname | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.identifier.doi | 10.1021/ja513112r | - |
dc.contributor.localauthor | Han, Sang-Woo | - |
dc.contributor.localauthor | Lee, Yunho | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | REDOX-ACTIVE LIGANDS | - |
dc.subject.keywordPlus | H OXIDATIVE ADDITION | - |
dc.subject.keywordPlus | CARBON-DIOXIDE | - |
dc.subject.keywordPlus | ALKOXIDE COMPLEXES | - |
dc.subject.keywordPlus | BOND ACTIVATION | - |
dc.subject.keywordPlus | PINCER LIGANDS | - |
dc.subject.keywordPlus | CO2 FIXATION | - |
dc.subject.keywordPlus | CATALYSIS | - |
dc.subject.keywordPlus | REACTIVITY | - |
dc.subject.keywordPlus | COMPOUND | - |
dc.subject.keywordPlus | REDOX-ACTIVE LIGANDS | - |
dc.subject.keywordPlus | H OXIDATIVE ADDITION | - |
dc.subject.keywordPlus | CARBON-DIOXIDE | - |
dc.subject.keywordPlus | ALKOXIDE COMPLEXES | - |
dc.subject.keywordPlus | BOND ACTIVATION | - |
dc.subject.keywordPlus | PINCER LIGANDS | - |
dc.subject.keywordPlus | CO2 FIXATION | - |
dc.subject.keywordPlus | CATALYSIS | - |
dc.subject.keywordPlus | REACTIVITY | - |
dc.subject.keywordPlus | COMPOUND | - |
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