DC Field | Value | Language |
---|---|---|
dc.contributor.author | Woo, Hyein | ko |
dc.contributor.author | Jang, Eunyoung | ko |
dc.contributor.author | Kim, Jin | ko |
dc.contributor.author | Lee, Yunho | ko |
dc.contributor.author | Kim, Jongsik | ko |
dc.contributor.author | You, Tae-Soo | ko |
dc.date.accessioned | 2015-06-24T02:13:25Z | - |
dc.date.available | 2015-06-24T02:13:25Z | - |
dc.date.created | 2015-06-08 | - |
dc.date.created | 2015-06-08 | - |
dc.date.created | 2015-06-08 | - |
dc.date.issued | 2015-04 | - |
dc.identifier.citation | INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, v.16, no.4, pp.9017 - 9036 | - |
dc.identifier.issn | 1422-0067 | - |
dc.identifier.uri | http://hdl.handle.net/10203/198955 | - |
dc.description.abstract | Three quinary polar intermetallic compounds in the (Eu1-xCax)(9)In-8(Ge1-ySny)(8) (x = 0.66, y = 0.03) and the (Eu1-xCax)(3)In(Ge3-ySn1+y) (x = 0.66, 0.68; y = 0.13, 0.27) phases have been synthesized using the molten In-metal flux method, and the crystal structures are characterized by powder and single-crystal X-ray diffractions. Two orthorhombic structural types can be viewed as an assembly of polyanionic frameworks consisting of the In(Ge/Sn)(4) tetrahedral chains, the bridging Ge-2 dimers, either the annulene-like 12-membered rings for the (Eu1-xCax)(9)In-8(Ge1-ySny)(8) series or the cis-trans Ge/Sn-chains for the (Eu1-xCax)(3)In(Ge3-ySn1+y) series, and several Eu/Ca-mixed cations. The most noticeable difference between two structural types is the amount and the location of the Sn-substitution for Ge: only a partial substitution (11%) occurs at the In(Ge/Sn)(4) tetrahedron in the (Eu1-xCax)(9)In-8(Ge1-ySny)(8) series, whereas both a complete and a partial substitution (up to 27%) are observed, respectively, at the cis-trans Ge/Sn-chain and at the In(Ge/Sn)(4) tetrahedron in the (Eu1-xCax)(3)In(Ge3-ySn1+y) series. A series of tight-binding linear muffin-tin orbital calculations is conducted to understand overall electronic structures and chemical bonding among components. Magnetic susceptibility measurement indicates a ferromagnetic ordering of Eu atoms below 5 K for Eu1.02(1)Ca1.98InGe2.87(1)Sn1.13. | - |
dc.language | English | - |
dc.publisher | MDPI AG | - |
dc.subject | LOCALIZATION FUNCTIONS | - |
dc.subject | SITE-PREFERENCE | - |
dc.subject | LI | - |
dc.subject | TRANSITION | - |
dc.subject | SYSTEM | - |
dc.subject | SERIES | - |
dc.subject | SR | - |
dc.subject | EU | - |
dc.subject | GE | - |
dc.subject | CE | - |
dc.title | Crystal Structure, Chemical Bonding and Magnetism Studies for Three Quinary Polar Intermetallic Compounds in the (Eu1-xCax)(9)In-8(Ge1-ySny)(8) (x=0.66, y=0.03) and the (Eu1-xCax)(3)In(Ge3-ySn1+y) (x=0.66, 0.68; y=0.13, 0.27) Phases | - |
dc.type | Article | - |
dc.identifier.wosid | 000354040400143 | - |
dc.identifier.scopusid | 2-s2.0-84961179227 | - |
dc.type.rims | ART | - |
dc.citation.volume | 16 | - |
dc.citation.issue | 4 | - |
dc.citation.beginningpage | 9017 | - |
dc.citation.endingpage | 9036 | - |
dc.citation.publicationname | INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES | - |
dc.identifier.doi | 10.3390/ijms16049017 | - |
dc.contributor.localauthor | Lee, Yunho | - |
dc.contributor.nonIdAuthor | Woo, Hyein | - |
dc.contributor.nonIdAuthor | Jang, Eunyoung | - |
dc.contributor.nonIdAuthor | Kim, Jongsik | - |
dc.contributor.nonIdAuthor | You, Tae-Soo | - |
dc.description.isOpenAccess | Y | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | polar intermetallics | - |
dc.subject.keywordAuthor | electronic structure | - |
dc.subject.keywordAuthor | chemical bonding | - |
dc.subject.keywordAuthor | single-crystal X-ray diffraction | - |
dc.subject.keywordAuthor | magnetism | - |
dc.subject.keywordAuthor | polar intermetallics | - |
dc.subject.keywordAuthor | electronic structure | - |
dc.subject.keywordAuthor | chemical bonding | - |
dc.subject.keywordAuthor | single-crystal X-ray diffraction | - |
dc.subject.keywordAuthor | magnetism | - |
dc.subject.keywordPlus | LOCALIZATION FUNCTIONS | - |
dc.subject.keywordPlus | SITE-PREFERENCE | - |
dc.subject.keywordPlus | LI | - |
dc.subject.keywordPlus | TRANSITION | - |
dc.subject.keywordPlus | SYSTEM | - |
dc.subject.keywordPlus | SERIES | - |
dc.subject.keywordPlus | SR | - |
dc.subject.keywordPlus | EU | - |
dc.subject.keywordPlus | GE | - |
dc.subject.keywordPlus | CE | - |
dc.subject.keywordPlus | LOCALIZATION FUNCTIONS | - |
dc.subject.keywordPlus | SITE-PREFERENCE | - |
dc.subject.keywordPlus | LI | - |
dc.subject.keywordPlus | TRANSITION | - |
dc.subject.keywordPlus | SYSTEM | - |
dc.subject.keywordPlus | SERIES | - |
dc.subject.keywordPlus | SR | - |
dc.subject.keywordPlus | EU | - |
dc.subject.keywordPlus | GE | - |
dc.subject.keywordPlus | CE | - |
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