DC Field | Value | Language |
---|---|---|
dc.contributor.author | Dateer, Ramesh B. | ko |
dc.contributor.author | Chang, Suk-Bok | ko |
dc.date.accessioned | 2015-06-04T05:49:04Z | - |
dc.date.available | 2015-06-04T05:49:04Z | - |
dc.date.created | 2015-06-01 | - |
dc.date.created | 2015-06-01 | - |
dc.date.created | 2015-06-01 | - |
dc.date.issued | 2015-04 | - |
dc.identifier.citation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.137, no.15, pp.4908 - 4911 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/10203/198786 | - |
dc.description.abstract | The first example of Rh(III)-catalyzed cyclization of arylnitrones to indolines under external oxidant-free conditions is presented. An intermolecular coupling of arylnitrones with internal alkynes is made possible by the dual role of the Cp*Rh(III) catalyst mediating both the C-H bond activation and O-atom transfer. Synthetically important and pharmacologically privileged indoline derivatives were obtained in good yields with high diastereoselectivity. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | QUINOLINE N-OXIDES | - |
dc.subject | BOND FUNCTIONALIZATION | - |
dc.subject | RHODIUM CATALYSIS | - |
dc.subject | STEREOSELECTIVE-SYNTHESIS | - |
dc.subject | DIRECTING GROUP | - |
dc.subject | ALKYNES | - |
dc.subject | NITRONES | - |
dc.subject | PALLADIUM | - |
dc.subject | CYCLOADDITION | - |
dc.subject | INDOLES | - |
dc.title | Selective Cyclization of Arylnitrones to Indolines under External Oxidant-Free Conditions: Dual Role of Rh(III) Catalyst in the C-H Activation and Oxygen Atom Transfer | - |
dc.type | Article | - |
dc.identifier.wosid | 000353606700009 | - |
dc.identifier.scopusid | 2-s2.0-84928494419 | - |
dc.type.rims | ART | - |
dc.citation.volume | 137 | - |
dc.citation.issue | 15 | - |
dc.citation.beginningpage | 4908 | - |
dc.citation.endingpage | 4911 | - |
dc.citation.publicationname | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.identifier.doi | 10.1021/jacs.5b01065 | - |
dc.contributor.localauthor | Chang, Suk-Bok | - |
dc.contributor.nonIdAuthor | Dateer, Ramesh B. | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | QUINOLINE N-OXIDES | - |
dc.subject.keywordPlus | BOND FUNCTIONALIZATION | - |
dc.subject.keywordPlus | RHODIUM CATALYSIS | - |
dc.subject.keywordPlus | STEREOSELECTIVE-SYNTHESIS | - |
dc.subject.keywordPlus | DIRECTING GROUP | - |
dc.subject.keywordPlus | ALKYNES | - |
dc.subject.keywordPlus | NITRONES | - |
dc.subject.keywordPlus | PALLADIUM | - |
dc.subject.keywordPlus | CYCLOADDITION | - |
dc.subject.keywordPlus | INDOLES | - |
dc.subject.keywordPlus | QUINOLINE N-OXIDES | - |
dc.subject.keywordPlus | BOND FUNCTIONALIZATION | - |
dc.subject.keywordPlus | RHODIUM CATALYSIS | - |
dc.subject.keywordPlus | STEREOSELECTIVE-SYNTHESIS | - |
dc.subject.keywordPlus | DIRECTING GROUP | - |
dc.subject.keywordPlus | ALKYNES | - |
dc.subject.keywordPlus | NITRONES | - |
dc.subject.keywordPlus | PALLADIUM | - |
dc.subject.keywordPlus | CYCLOADDITION | - |
dc.subject.keywordPlus | INDOLES | - |
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