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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Iridium(III)-Catalyzed C-H Amidation of Arylphosphoryls Leading to a P-Stereogenic Center

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dc.contributor.authorKwon, Donghyunko
dc.contributor.authorLee, Dong Gunko
dc.contributor.authorKim, Jiyuko
dc.contributor.authorPark, Sehoonko
dc.contributor.authorChang, Sukbokko
dc.date.accessioned2015-03-27T08:02:39Z-
dc.date.available2015-03-27T08:02:39Z-
dc.date.created2014-11-04-
dc.date.created2014-11-04-
dc.date.issued2014-09-
dc.identifier.citationCHEMISTRY-A EUROPEAN JOURNAL, v.20, no.39, pp.12421 - 12425-
dc.identifier.issn0947-6539-
dc.identifier.urihttp://hdl.handle.net/10203/194526-
dc.description.abstractDirect C-H amidation of arylphosphoryl compounds has been developed by using an Ir-III catalyst system under mild conditions. A wide range of substrates could be employed with high functional-group tolerance. This procedure was successfully applied for the first time to the asymmetric reaction giving rise to a P-chirogenic center with a high diastereomeric ratio of up to 19:1 (90% de).-
dc.languageEnglish-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectCARBON-HYDROGEN BONDS-
dc.subjectPHOSPHORUS-COMPOUNDS-
dc.subjectASYMMETRIC-SYNTHESIS-
dc.subjectNATURAL-PRODUCTS-
dc.subjectNITROGEN-SOURCE-
dc.subjectACTIVATION-
dc.subjectARYLATION-
dc.subjectARENES-
dc.subjectAZIDES-
dc.subjectFUNCTIONALIZATION-
dc.titleIridium(III)-Catalyzed C-H Amidation of Arylphosphoryls Leading to a P-Stereogenic Center-
dc.typeArticle-
dc.identifier.wosid000342626200013-
dc.identifier.scopusid2-s2.0-84982256685-
dc.type.rimsART-
dc.citation.volume20-
dc.citation.issue39-
dc.citation.beginningpage12421-
dc.citation.endingpage12425-
dc.citation.publicationnameCHEMISTRY-A EUROPEAN JOURNAL-
dc.identifier.doi10.1002/chem.201404151-
dc.contributor.localauthorChang, Sukbok-
dc.contributor.nonIdAuthorPark, Sehoon-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorasymmetric induction-
dc.subject.keywordAuthorC-H functionalization-
dc.subject.keywordAuthorchirality-
dc.subject.keywordAuthoriridium catalysis-
dc.subject.keywordAuthorphosphine oxides-
dc.subject.keywordPlusCARBON-HYDROGEN BONDS-
dc.subject.keywordPlusPHOSPHORUS-COMPOUNDS-
dc.subject.keywordPlusASYMMETRIC-SYNTHESIS-
dc.subject.keywordPlusNATURAL-PRODUCTS-
dc.subject.keywordPlusNITROGEN-SOURCE-
dc.subject.keywordPlusACTIVATION-
dc.subject.keywordPlusARYLATION-
dc.subject.keywordPlusARENES-
dc.subject.keywordPlusAZIDES-
dc.subject.keywordPlusFUNCTIONALIZATION-
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CH-Journal Papers(저널논문)
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