Iridium-Catalyzed C-H Amination with Anilines at Room Temperature: Compatibility of Iridacycles with External Oxidants

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Described herein is the development of an iridium-catalyzed direct C-H amination of benzamides with anilines at room temperature, representing a unique example of an Ir catalyst system that is compatible with external oxidants. Mechanistic details, such as the isolation and characterization of key iridacycle intermediates, are also discussed.
Publisher
AMER CHEMICAL SOC
Issue Date
2014-04
Language
English
Article Type
Article
Keywords

BOND ACTIVATION; COUPLING REACTIONS; NATURAL-PRODUCTS; DIRECTING GROUPS; DIRECT ARYLATION; NITROGEN-SOURCE; N-CHLOROAMINES; ATOM TRANSFER; ARYL AZIDES; AMIDATION

Citation

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.136, no.16, pp.5904 - 5907

ISSN
0002-7863
DOI
10.1021/ja502270y
URI
http://hdl.handle.net/10203/189170
Appears in Collection
CH-Journal Papers(저널논문)
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