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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Orthogonal Reactivity of Acyl Azides in C-H Activation: Dichotomy between C-C and C-N Amidations Based on Catalyst Systems

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dc.contributor.authorShin, Kwangminko
dc.contributor.authorRyu, Jaeyuneko
dc.contributor.authorChang, Sukbokko
dc.date.accessioned2014-08-29T02:54:42Z-
dc.date.available2014-08-29T02:54:42Z-
dc.date.created2014-05-13-
dc.date.created2014-05-13-
dc.date.created2014-05-13-
dc.date.issued2014-04-
dc.identifier.citationORGANIC LETTERS, v.16, no.7, pp.2022 - 2025-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10203/189038-
dc.description.abstractThe dual reactivity of acyl azides was utilized successfully in C-H activation by the choice of catalyst systems: while selective C-C amidation was achieved under thermal Rh catalysis, a Ru catalyst was found to mediate direct C-N amidation also highly selectively. Investigations of the mechanistic dichotomy between two catalytic systems are also presented.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectBOND ACTIVATION-
dc.subjectARYL AZIDES-
dc.subjectCONVERGENT SYNTHESIS-
dc.subjectRHODIUM CATALYSIS-
dc.subjectDIRECT ARYLATIONS-
dc.subjectNITROGEN-SOURCE-
dc.subjectAMINATION-
dc.subjectARENES-
dc.subjectFUNCTIONALIZATION-
dc.subjectCOMPLEXES-
dc.titleOrthogonal Reactivity of Acyl Azides in C-H Activation: Dichotomy between C-C and C-N Amidations Based on Catalyst Systems-
dc.typeArticle-
dc.identifier.wosid000334016600049-
dc.identifier.scopusid2-s2.0-84898716383-
dc.type.rimsART-
dc.citation.volume16-
dc.citation.issue7-
dc.citation.beginningpage2022-
dc.citation.endingpage2025-
dc.citation.publicationnameORGANIC LETTERS-
dc.identifier.doi10.1021/ol500602b-
dc.embargo.liftdate9999-12-31-
dc.embargo.terms9999-12-31-
dc.contributor.localauthorChang, Sukbok-
dc.type.journalArticleArticle-
dc.subject.keywordPlusBOND ACTIVATION-
dc.subject.keywordPlusARYL AZIDES-
dc.subject.keywordPlusCONVERGENT SYNTHESIS-
dc.subject.keywordPlusRHODIUM CATALYSIS-
dc.subject.keywordPlusDIRECT ARYLATIONS-
dc.subject.keywordPlusNITROGEN-SOURCE-
dc.subject.keywordPlusAMINATION-
dc.subject.keywordPlusARENES-
dc.subject.keywordPlusFUNCTIONALIZATION-
dc.subject.keywordPlusCOMPLEXES-
dc.subject.keywordPlusBOND ACTIVATION-
dc.subject.keywordPlusARYL AZIDES-
dc.subject.keywordPlusCONVERGENT SYNTHESIS-
dc.subject.keywordPlusRHODIUM CATALYSIS-
dc.subject.keywordPlusDIRECT ARYLATIONS-
dc.subject.keywordPlusNITROGEN-SOURCE-
dc.subject.keywordPlusAMINATION-
dc.subject.keywordPlusARENES-
dc.subject.keywordPlusFUNCTIONALIZATION-
dc.subject.keywordPlusCOMPLEXES-
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