Synergism between CdTe semiconductor and pyridine - photoenhanced electrocatalysis for CO2 reduction to formic acid

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The cooperative effect of pyridine catalysis with photoenhanced electrochemical reduction by CdTe/FTO of CO2 is explored. The enhancement of overall formic acid production and high faradaic efficiency is due to the increased photocurrent of CdTe/FTO upon irradiation and the decrease in activation barrier due to the formation of a pyridine-CO2 intermediate.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
2014
Language
English
Article Type
Article
Keywords

CARBON-DIOXIDE; SOLAR-CELLS; PHOTOELECTROCATALYTIC REDUCTION; ELECTROCHEMICAL REDUCTION; PHOTOCATALYTIC REDUCTION; METHANOL; COMPLEXES; CATALYSTS; INSIGHTS

Citation

RSC ADVANCES, v.4, no.6, pp.3016 - 3019

ISSN
2046-2069
DOI
10.1039/c3ra44410d
URI
http://hdl.handle.net/10203/188920
Appears in Collection
CBE-Journal Papers(저널논문)
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