DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Jeongmook | ko |
dc.contributor.author | Kim, Soyeon | ko |
dc.contributor.author | Kim, Sangkyu | ko |
dc.date.accessioned | 2014-08-29T01:50:54Z | - |
dc.date.available | 2014-08-29T01:50:54Z | - |
dc.date.created | 2014-04-28 | - |
dc.date.created | 2014-04-28 | - |
dc.date.issued | 2014-03 | - |
dc.identifier.citation | JOURNAL OF PHYSICAL CHEMISTRY A, v.118, no.10, pp.1850 - 1857 | - |
dc.identifier.issn | 1089-5639 | - |
dc.identifier.uri | http://hdl.handle.net/10203/188880 | - |
dc.description.abstract | Two distinct rotational isomers of thioanisole-d(1) (C6H5S-CH2D) and thioanisole-d(2) (C6H5S-CHD2) with respect to the internal rotation of the methyl moiety have been identified and characterized spectroscopically using the resonantly enhanced two photon ionization, UV-UV hole burning, and slow-electron velocity map imaging techniques. From the statistical weights, the definite assignment for the specific rotational isomer of each isotopomer has been successfully done, providing isomer-specific ionization energies and vibrational frequencies of S-1/D-0 states. Detailed molecular structures, the methyl internal-rotor barrier, and normal-mode descriptions for selective vibrations are discussed with the aid of | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | RESOLVED ELECTRONIC-SPECTRA | - |
dc.subject | EXCITED-STATE | - |
dc.subject | P-FLUOROTOLUENE | - |
dc.subject | DYNAMICS | - |
dc.subject | ETHANE | - |
dc.subject | FIELD | - |
dc.subject | CONFORMATION | - |
dc.subject | COMPLEXES | - |
dc.subject | CATIONS | - |
dc.subject | MODEL | - |
dc.title | Spectroscopic Separation of the Methyl Internal-Rotational Isomers of Thioanisole Isotopomers (C6H5S-CH2D and C6H5S-CHD2) | - |
dc.type | Article | - |
dc.identifier.wosid | 000333006100012 | - |
dc.identifier.scopusid | 2-s2.0-84896267505 | - |
dc.type.rims | ART | - |
dc.citation.volume | 118 | - |
dc.citation.issue | 10 | - |
dc.citation.beginningpage | 1850 | - |
dc.citation.endingpage | 1857 | - |
dc.citation.publicationname | JOURNAL OF PHYSICAL CHEMISTRY A | - |
dc.identifier.doi | 10.1021/jp5003676 | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Kim, Sangkyu | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | RESOLVED ELECTRONIC-SPECTRA | - |
dc.subject.keywordPlus | EXCITED-STATE | - |
dc.subject.keywordPlus | P-FLUOROTOLUENE | - |
dc.subject.keywordPlus | DYNAMICS | - |
dc.subject.keywordPlus | ETHANE | - |
dc.subject.keywordPlus | FIELD | - |
dc.subject.keywordPlus | CONFORMATION | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | CATIONS | - |
dc.subject.keywordPlus | MODEL | - |
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