Facile N-N coupling and copper (II) promoted cleavage of N,N -linked N-methylbenzimidazole
Together with the facile and high yielding formation of N,N'-linked NHC ligand, the complexation of Nmethylbenzimiclazole (1a), N-methylbenzimcliazolium chloride (4a) and N,N,-Iinked NHC ligand, 3,3-dimethyl-1,1-bibenzimidazolium dichloride (2a), with CuO or CuCl(2) give a dichloro-bridged binuclear copper(II) species (la), as characterized by IR spectroscopy and X-ray. (C) 2008 Elsevier B.V. All rights reserved.
- Publisher
- ELSEVIER SCIENCE BV
- Issue Date
- 2008-10
- Language
- English
- Article Type
- Article
- Keywords
BIS(N-HETEROCYCLIC CARBENE) COMPLEXES; HETEROCYCLIC CARBENES; HECK REACTION; IONIC LIQUIDS; PALLADIUM(II) COMPLEXES; BISCARBENE COMPLEXES; NHC LIGANDS; REACTIVITY; DERIVATIVES; CATALYSTS
- Citation
INORGANIC CHEMISTRY COMMUNICATIONS, v.11, no.10, pp.1170 - 1173
- ISSN
- 1387-7003
- Appears in Collection
- CH-Journal Papers(저널논문)
- Files in This Item
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