Shortcut method for kinetically controlled reactive distillation systems

Abstract

A geometric-based shortcut method for reactive distillation is addressed. The rectification body method for nonreactive distillation, the concept of critical Damkohler numbers, and the geometric design method for reactive distillation are combined with a new eigenvector analysis of pinch points. This shortcut method provides a minimum or reasonable Damkohler number for a given heat duty, as well as the design implication of how, to effectively distribute reaction zones inside a column. This method can be used for a fast screening of process design alternatives and for an initialization of rigorous optimization.