Synthesis of visible light-active CeO2 sheets via mussel-inspired CaCO3 mineralization

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Visible light-active, nano-grained CeO2 sheets are successfully synthesized using polydopamine-induced CaCO3 vaterite microspheres. The nano-grained CeO2 sheets exhibited a distinct polycrystalline sheet-like structure with grains, with a red-shift in the UV-visible absorption spectrum and a much narrower bandgap (2.71-2.83 eV). Visible light-responsive photocatalytic activity was observed with nano-grained CeO2 sheets at a rate constant that was much higher than that of CeO2 nanoparticles.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
2013-01
Language
English
Article Type
Article
Keywords

CO OXIDATION; MULTIFUNCTIONAL COATINGS; DOPED CEO2; FUEL-CELL; NANOPARTICLES; SURFACE; WATER; OXIDE; DEGRADATION; IRRADIATION

Citation

JOURNAL OF MATERIALS CHEMISTRY A, v.1, no.2, pp.241 - 245

ISSN
2050-7488
DOI
10.1039/c2ta00782g
URI
http://hdl.handle.net/10203/174634
Appears in Collection
MS-Journal Papers(저널논문)
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