DC Field | Value | Language |
---|---|---|
dc.contributor.author | Khatua, Snehadrinarayan | ko |
dc.contributor.author | Kim, Ki-Bong | ko |
dc.contributor.author | Kang, Jina | ko |
dc.contributor.author | Huh, Jung-Oh | ko |
dc.contributor.author | Hong, Chang-Seop | ko |
dc.contributor.author | Churchill, David G | ko |
dc.date.accessioned | 2010-03-31T09:06:24Z | - |
dc.date.available | 2010-03-31T09:06:24Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2009-08 | - |
dc.identifier.citation | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, no.22, pp.3266 - 3274 | - |
dc.identifier.issn | 1434-1948 | - |
dc.identifier.uri | http://hdl.handle.net/10203/17462 | - |
dc.description.abstract | Two chiral dimeric Cu-II Schiff base complexes, Na-2[Cu(S-lys)(2)center dot(H2O)(2)]center dot(ClO4)(2) (1) and [Cu(S-ornH)(2)center dot(H2O)(2)]center dot(ClO4)(2) (2) have been prepared by an easy one-pot method in which the L-lysine and L-ornithine-based Schiff base ligands are generated in situ. These complexes have been characterized by various spectroscopic techniques and single-crystal X-ray diffraction. The molecular structures show that both complexes are indeed dimeric with Cu-II centers that are phenolate-bridged. Variable-temperature magnetic analysis revealed that a strong antiferromagnetic coupling interaction was mediated through the phenolate bridge between the two Cu-II centers. Since these compounds were highly soluble in water, we explored carboxylate sensing capability through colorimetric indicator displacement assays (IDAs). By using pyrocatechol violet (PV) as a displaceable colorimetric indicator, citrate ion selectivity was demonstrated in 100% water solution in the physiological pH range. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009) | - |
dc.description.sponsorship | support from Korea Science and Engineering Foundation (KOSEF) (grant no. R01-2008-000-12388-0) | en |
dc.language | English | - |
dc.language.iso | en_US | en |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | BASE COPPER(II) COMPLEXES | - |
dc.subject | REDUCED SCHIFF-BASE | - |
dc.subject | INDICATOR-DISPLACEMENT ASSAYS | - |
dc.subject | TEACHING OLD INDICATORS | - |
dc.subject | NAKED-EYE DETECTION | - |
dc.subject | CRYSTAL-STRUCTURES | - |
dc.subject | DICOPPER(II) COMPLEXES | - |
dc.subject | COORDINATION CHEMISTRY | - |
dc.subject | CHEMOSENSING ENSEMBLE | - |
dc.subject | DICARBOXYLATE ANIONS | - |
dc.title | Synthesis, Structure, Magnetic Properties and Aqueous Optical Citrate Detection of Chiral Dinuclear Cu-II Complexes | - |
dc.type | Article | - |
dc.identifier.wosid | 000268817300007 | - |
dc.identifier.scopusid | 2-s2.0-67949089556 | - |
dc.type.rims | ART | - |
dc.citation.issue | 22 | - |
dc.citation.beginningpage | 3266 | - |
dc.citation.endingpage | 3274 | - |
dc.citation.publicationname | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | - |
dc.identifier.doi | 10.1002/ejic.200900357 | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Churchill, David G | - |
dc.contributor.nonIdAuthor | Khatua, Snehadrinarayan | - |
dc.contributor.nonIdAuthor | Huh, Jung-Oh | - |
dc.contributor.nonIdAuthor | Hong, Chang-Seop | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Chiral dicopper complex | - |
dc.subject.keywordAuthor | Schiff bases | - |
dc.subject.keywordAuthor | Magnetic properties | - |
dc.subject.keywordAuthor | Structure elucidation | - |
dc.subject.keywordAuthor | Citrate detection | - |
dc.subject.keywordPlus | BASE COPPER(II) COMPLEXES | - |
dc.subject.keywordPlus | REDUCED SCHIFF-BASE | - |
dc.subject.keywordPlus | INDICATOR-DISPLACEMENT ASSAYS | - |
dc.subject.keywordPlus | TEACHING OLD INDICATORS | - |
dc.subject.keywordPlus | NAKED-EYE DETECTION | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURES | - |
dc.subject.keywordPlus | DICOPPER(II) COMPLEXES | - |
dc.subject.keywordPlus | COORDINATION CHEMISTRY | - |
dc.subject.keywordPlus | CHEMOSENSING ENSEMBLE | - |
dc.subject.keywordPlus | DICARBOXYLATE ANIONS | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.