DC Field | Value | Language |
---|---|---|
dc.contributor.author | Song, Chang Eun | ko |
dc.contributor.author | Kang, In-Nam | ko |
dc.contributor.author | Kim, Ji-Hoon | ko |
dc.contributor.author | Hwang, Do-Hoon | ko |
dc.contributor.author | Lee, JC | ko |
dc.contributor.author | Ahn, Taek | ko |
dc.contributor.author | Shin, Won Suk | ko |
dc.contributor.author | Moon, Sang-Jin | ko |
dc.contributor.author | Lee, Sang Kyu | ko |
dc.date.accessioned | 2013-08-08T05:42:41Z | - |
dc.date.available | 2013-08-08T05:42:41Z | - |
dc.date.created | 2013-04-02 | - |
dc.date.created | 2013-04-02 | - |
dc.date.issued | 2013-04 | - |
dc.identifier.citation | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, v.51, no.7, pp.1512 - 1519 | - |
dc.identifier.issn | 0887-624X | - |
dc.identifier.uri | http://hdl.handle.net/10203/174511 | - |
dc.description.abstract | A set of novel conjugated polyfluorene co- polymers, poly[(9,9-didecylfluorene-2,7-diyl)-co-(4,7-di-2-thienyl- 2,1,3-benzothiadiazole-5,5-diyl)-co-(pyrene-1,6-diyl)], are synthesized via Pd(II)-mediated polymerization from 2,7-bis(4,4,5, 5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9,9-di-n-decylfluorene, 4, 7-di(2-bromothien-5-yl)-2,1,3-benzothiadiazole, and 1,6-dibromopyrene with a variety of monomer molar ratios. The field-effect carrier mobilities and optical, electrochemical, and photovoltaic properties of the copolymers are systematically investigated. The hole mobilities of the copolymers are found to be in the range 7.0 x 105 8.0 x 104 cm2 V1 s1 and the on/off ratios were 8 x 103 7 x 104. Conventional polymer solar cells (PSCs) with the configuration ITO/PEDOT:PSS/polymer:PC71BM/LiF/Al are fabricated. Under optimized conditions, the polymers display power conversion efficiencies (PCEs) for the PSCs in the range 1.993.37% under AM 1.5 illumination (100 mW cm2). Among the four copolymers, P2, containing a 2.5 mol % pyrene component incorporated into poly[9,9-didecylfluorene-alt-5,5-(4,7-di-2-thienyl-2,1,3-benzothiadiazole)] (PFDTBT) displays a PCE of 3.37% with a short circuit current of 9.15 mA cm2, an open circuit voltage of 0.86 V, and a fill factor of 0.43, under AM 1.5 illumination (100 mW cm2). (c) 2013 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013, 51, 1512,-1519 | - |
dc.language | English | - |
dc.publisher | WILEY-BLACKWELL | - |
dc.subject | POLYMER SOLAR-CELLS | - |
dc.subject | DONOR-ACCEPTOR COPOLYMERS | - |
dc.subject | LIGHT-EMITTING DIODES | - |
dc.subject | CONJUGATED POLYMERS | - |
dc.subject | BAND-GAP | - |
dc.subject | POLYFLUORENE | - |
dc.subject | EFFICIENCY | - |
dc.subject | ABSORPTION | - |
dc.subject | BLENDS | - |
dc.title | Photovoltaic performance enhancement using fluorene-based copolymers containing pyrene units | - |
dc.type | Article | - |
dc.identifier.wosid | 000315495100003 | - |
dc.identifier.scopusid | 2-s2.0-84874590723 | - |
dc.type.rims | ART | - |
dc.citation.volume | 51 | - |
dc.citation.issue | 7 | - |
dc.citation.beginningpage | 1512 | - |
dc.citation.endingpage | 1519 | - |
dc.citation.publicationname | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | - |
dc.identifier.doi | 10.1002/pola.26525 | - |
dc.contributor.nonIdAuthor | Kang, In-Nam | - |
dc.contributor.nonIdAuthor | Kim, Ji-Hoon | - |
dc.contributor.nonIdAuthor | Hwang, Do-Hoon | - |
dc.contributor.nonIdAuthor | Lee, JC | - |
dc.contributor.nonIdAuthor | Ahn, Taek | - |
dc.contributor.nonIdAuthor | Shin, Won Suk | - |
dc.contributor.nonIdAuthor | Moon, Sang-Jin | - |
dc.contributor.nonIdAuthor | Lee, Sang Kyu | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | conducting polymers | - |
dc.subject.keywordAuthor | conjugated polymers | - |
dc.subject.keywordAuthor | fluorene-based copolymers | - |
dc.subject.keywordAuthor | organic electronic materials | - |
dc.subject.keywordAuthor | polymer solar cells | - |
dc.subject.keywordAuthor | pyrene | - |
dc.subject.keywordAuthor | thin films | - |
dc.subject.keywordPlus | POLYMER SOLAR-CELLS | - |
dc.subject.keywordPlus | LIGHT-EMITTING-DIODES | - |
dc.subject.keywordPlus | DONOR-ACCEPTOR COPOLYMERS | - |
dc.subject.keywordPlus | CONJUGATED POLYMERS | - |
dc.subject.keywordPlus | BLEND FILMS | - |
dc.subject.keywordPlus | BAND-GAP | - |
dc.subject.keywordPlus | POLYFLUORENE | - |
dc.subject.keywordPlus | EFFICIENCY | - |
dc.subject.keywordPlus | ABSORPTION | - |
dc.subject.keywordPlus | TRANSPORT | - |
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