Synthesis and structures of thienyl-substituted 5-dipyrromethane isomers

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dc.contributor.authorMaiti, Nko
dc.contributor.authorLee, Jko
dc.contributor.authorDo, Youngkyuko
dc.contributor.authorShin, HSko
dc.contributor.authorChurchill, David Gko
dc.date.accessioned2010-02-10T08:58:31Z-
dc.date.available2010-02-10T08:58:31Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2005-12-
dc.identifier.citationJOURNAL OF CHEMICAL CRYSTALLOGRAPHY, v.35, no.12, pp.949 - 955-
dc.identifier.issn1074-1542-
dc.identifier.urihttp://hdl.handle.net/10203/16607-
dc.description.abstractThe compounds 5(2-thienyl)-and 5(3-thienyl)-dipyrromethane (1 and2, respectively) have been synthesized and isolated from the acid-catalyzed reaction between thiophenes-carboxaldehyde and pyrrole. Characterization by X-ray diffraction confirms molecular structures involving twoortho-substituted pyrrolyl and one thienyl groups. Both the compounds1 and2 were crystallized in the monoclinic space groupP2(1)/n with cell parametersa = 5.7149(16) angstrom, b = 17.338(6) angstrom, and c = 11.785(4) angstrom, beta = 98.466(9)degrees,V = 1155.0(6) angstrom(3) for compound1; and a = 5.828(4) angstrom, b = 17.424(10) angstrom, c = 11.822(8) angstrom, beta = 98.10(2)degrees, and V = 1188.4(13) angstrom(3) for compound 2.-
dc.description.sponsorshipthe financial support from the Korea Advanced Institute of Science and Technology (KAIST) , the BK 21 Project and the CMDSen
dc.languageEnglish-
dc.language.isoen_USen
dc.publisherSPRINGER/PLENUM PUBLISHERS-
dc.subjectTRANS-A(2)B-CORROLES-
dc.subjectBEARING-
dc.subjectCORROLES-
dc.subjectROUTE-
dc.titleSynthesis and structures of thienyl-substituted 5-dipyrromethane isomers-
dc.typeArticle-
dc.identifier.wosid000234396000003-
dc.identifier.scopusid2-s2.0-29944445717-
dc.type.rimsART-
dc.citation.volume35-
dc.citation.issue12-
dc.citation.beginningpage949-
dc.citation.endingpage955-
dc.citation.publicationnameJOURNAL OF CHEMICAL CRYSTALLOGRAPHY-
dc.identifier.doi10.1007/s10870-005-5178-9-
dc.embargo.liftdate9999-12-31-
dc.embargo.terms9999-12-31-
dc.contributor.localauthorDo, Youngkyu-
dc.contributor.localauthorChurchill, David G-
dc.contributor.nonIdAuthorMaiti, N-
dc.contributor.nonIdAuthorLee, J-
dc.contributor.nonIdAuthorShin, HS-
dc.type.journalArticleArticle-
dc.subject.keywordAuthor5-dipyrromethane-
dc.subject.keywordAuthorcrystal structure-
dc.subject.keywordAuthorcorrole precursor-
dc.subject.keywordPlusTRANS-A(2)B-CORROLES-
dc.subject.keywordPlusBEARING-
dc.subject.keywordPlusCORROLES-
dc.subject.keywordPlusROUTE-
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