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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

The OH production from the pi-pi* transition of acetylacetone

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dc.contributor.authorYoon, MCko
dc.contributor.authorChoi, YSko
dc.contributor.authorKim, Sangkyuko
dc.date.accessioned2009-12-04T01:19:10Z-
dc.date.available2009-12-04T01:19:10Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued1999-01-
dc.identifier.citationCHEMICAL PHYSICS LETTERS, v.300, no.1-2, pp.207 - 212-
dc.identifier.issn0009-2614-
dc.identifier.urihttp://hdl.handle.net/10203/14149-
dc.description.abstractAcetylacetone in its enolic form has been found to produce the OH radical as a photofragment after the pi-pi* transition induced by UV irradiation. The absorption spectrum of the enolic acetylacetone in the supersonic jet, deduced from the OH photofragment excitation spectrum, shows no distinct structures suggesting the very fast decay of the S-1 state being followed by the C-O chemical bond dissociation. The photodissociation mechanism is discussed with a qualitative description of the energetics involved. (C) 1999 Elsevier Science B.V. All rights reserved.-
dc.description.sponsorshipKorea Science and Engineering Foundation Inha Universityen
dc.languageEnglish-
dc.language.isoen_USen
dc.publisherELSEVIER SCIENCE BV-
dc.subjectELECTRON-DIFFRACTION-
dc.subjectPROTON-TRANSFER-
dc.subjectSPECTROSCOPY-
dc.subjectDISSOCIATION-
dc.subjectFORCE-
dc.subjectFORMS-
dc.subjectKETO-
dc.titleThe OH production from the pi-pi* transition of acetylacetone-
dc.typeArticle-
dc.identifier.wosid000078390700031-
dc.identifier.scopusid2-s2.0-0033613612-
dc.type.rimsART-
dc.citation.volume300-
dc.citation.issue1-2-
dc.citation.beginningpage207-
dc.citation.endingpage212-
dc.citation.publicationnameCHEMICAL PHYSICS LETTERS-
dc.identifier.doi10.1016/S0009-2614(98)01373-6-
dc.embargo.liftdate9999-12-31-
dc.embargo.terms9999-12-31-
dc.contributor.localauthorKim, Sangkyu-
dc.contributor.nonIdAuthorYoon, MC-
dc.contributor.nonIdAuthorChoi, YS-
dc.type.journalArticleArticle-
dc.subject.keywordPlusELECTRON-DIFFRACTION-
dc.subject.keywordPlusPROTON-TRANSFER-
dc.subject.keywordPlusSPECTROSCOPY-
dc.subject.keywordPlusDISSOCIATION-
dc.subject.keywordPlusFORCE-
dc.subject.keywordPlusFORMS-
dc.subject.keywordPlusKETO-
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