Framework characterization of mesostructured carbon CMK-1 by X-ray powder diffraction and electron microscopy

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The model of structure and structural transformation of the mesostructured carbon material CMK-1 was established by X-ray powder diffraction (XRD) and transmission electron microscopy (TEM) investigations. The investigations showed that the enantiomeric carbon subframeworks formed within the pores of the MCM48 mesoporous template used for the material synthesis displaced with respect to one another without significant distortions after the dissolution of the silica wall of the template. The model proposed agrees well with TEM images observed. The XRD structural modeling of CMK- I done using the continuous density function technique allowed perfect fit of the calculated to the experimental powder diffraction pattern and provided geometric characteristics of the material texture. The structural characteristics obtained agreed fairly well with TEM analysis and with previously reported adsorption data.
Publisher
AMER CHEMICAL SOC
Issue Date
2002-11
Language
English
Article Type
Article
Keywords

ORDERED MESOPOROUS CARBONS; MOLECULAR-SIEVES; TEMPLATE

Citation

JOURNAL OF PHYSICAL CHEMISTRY B, v.106, no.47, pp.12198 - 12202

ISSN
1520-6106
DOI
10.1021/jp0257653
URI
http://hdl.handle.net/10203/11237
Appears in Collection
CH-Journal Papers(저널논문)
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