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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Copper-Mediated Selective Cyanation of Indoles and 2-Phenylpyridines with Ammonium Iodide and DMF

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dc.contributor.authorKim, Jinhoko
dc.contributor.authorKim, Hyunwooko
dc.contributor.authorChang, Sukbokko
dc.date.accessioned2013-03-13T05:25:42Z-
dc.date.available2013-03-13T05:25:42Z-
dc.date.created2012-09-28-
dc.date.created2012-09-28-
dc.date.issued2012-08-
dc.identifier.citationORGANIC LETTERS, v.14, no.15, pp.3924 - 3927-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10203/104559-
dc.description.abstractCopper-mediated regioselective cyanation of indoles and 2-phenylpyridines was developed by using ammonium iodide and DMF as the combined source of a cyano unit under "Pd-free" conditions. Mechanistic studies indicate that the reaction of indoles proceeds through a two-step sequence: electrophilic initial iodination and then cyanation. The cyanation has a broad substrate scope, high functional group tolerance, and excellent regloselectivity.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectPALLADIUM-CATALYZED CYANATION-
dc.subjectC-H BONDS-
dc.subjectARYL HALIDES-
dc.subjectCONVENIENT PROCEDURE-
dc.subjectAROMATIC-COMPOUNDS-
dc.subjectDIRECT AMINATION-
dc.subjectBORONIC ACIDS-
dc.subjectFUNCTIONALIZATION-
dc.subjectBROMIDES-
dc.subjectCOMPLEXES-
dc.titleCopper-Mediated Selective Cyanation of Indoles and 2-Phenylpyridines with Ammonium Iodide and DMF-
dc.typeArticle-
dc.identifier.wosid000307041600029-
dc.identifier.scopusid2-s2.0-84864614778-
dc.type.rimsART-
dc.citation.volume14-
dc.citation.issue15-
dc.citation.beginningpage3924-
dc.citation.endingpage3927-
dc.citation.publicationnameORGANIC LETTERS-
dc.identifier.doi10.1021/ol301674m-
dc.contributor.localauthorChang, Sukbok-
dc.contributor.nonIdAuthorKim, Hyunwoo-
dc.type.journalArticleArticle-
dc.subject.keywordPlusPALLADIUM-CATALYZED CYANATION-
dc.subject.keywordPlusC-H BONDS-
dc.subject.keywordPlusARYL HALIDES-
dc.subject.keywordPlusCONVENIENT PROCEDURE-
dc.subject.keywordPlusAROMATIC-COMPOUNDS-
dc.subject.keywordPlusDIRECT AMINATION-
dc.subject.keywordPlusBORONIC ACIDS-
dc.subject.keywordPlusFUNCTIONALIZATION-
dc.subject.keywordPlusBROMIDES-
dc.subject.keywordPlusCOMPLEXES-
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CH-Journal Papers(저널논문)
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