Electrochemical Design of Mesoporous Pt-Ru Alloy Films with Various Compositions toward Superior Electrocatalytic Performance

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dc.contributor.authorWang, Hongjingko
dc.contributor.authorImura, Masatakako
dc.contributor.authorNemoto, Yoshihiroko
dc.contributor.authorWang, Liangko
dc.contributor.authorJeong, Hu Youngko
dc.contributor.authorYokoshima, Tokihikoko
dc.contributor.authorTerasaki, Osamuko
dc.contributor.authorYamauchi, Yusukeko
dc.date.accessioned2013-03-13T03:30:03Z-
dc.date.available2013-03-13T03:30:03Z-
dc.date.created2013-01-07-
dc.date.created2013-01-07-
dc.date.issued2012-
dc.identifier.citationCHEMISTRY-A EUROPEAN JOURNAL, v.18, no.41, pp.13142 - 13148-
dc.identifier.issn0947-6539-
dc.identifier.urihttp://hdl.handle.net/10203/104367-
dc.description.abstractMesoporous PtRu alloy films with various compositions were synthesized by electrochemical plating in an aqueous surfactant solution. After the removal of surfactants, continuous mesoporous PtRu alloy films possessing uniform mesopores with diameter about 7 nm were obtained. The Ru content in the films could be controlled from 0 to 13 at?% by changing the precursor compositions. For all the films, the mesostructural periodicities and the mesopore sizes in the films were not changed. Due to the mesoporous structure and the doped Ru content, our mesoporous PtRu films showed superior electrocatalytic activity for methanol oxidation reaction in comparison with the commercially available Pt catalyst.-
dc.languageEnglish-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectMETHANOL OXIDATION REACTION-
dc.subjectHIGHLY-ACTIVE ELECTROCATALYSTS-
dc.subjectAQUEOUS SURFACTANT SOLUTIONS-
dc.subjectPD BIMETALLIC NANODENDRITES-
dc.subjectSIZE-CONTROLLED SYNTHESIS-
dc.subjectHIGH CATALYTIC-ACTIVITY-
dc.subjectFACILE SYNTHESIS-
dc.subjectFUEL-CELLS-
dc.subjectPLATINUM NANOPARTICLES-
dc.subjectSOFT-TEMPLATE-
dc.titleElectrochemical Design of Mesoporous Pt-Ru Alloy Films with Various Compositions toward Superior Electrocatalytic Performance-
dc.typeArticle-
dc.identifier.wosid000309239300029-
dc.identifier.scopusid2-s2.0-84867055675-
dc.type.rimsART-
dc.citation.volume18-
dc.citation.issue41-
dc.citation.beginningpage13142-
dc.citation.endingpage13148-
dc.citation.publicationnameCHEMISTRY-A EUROPEAN JOURNAL-
dc.identifier.doi10.1002/chem.201201964-
dc.contributor.nonIdAuthorWang, Hongjing-
dc.contributor.nonIdAuthorImura, Masataka-
dc.contributor.nonIdAuthorNemoto, Yoshihiro-
dc.contributor.nonIdAuthorWang, Liang-
dc.contributor.nonIdAuthorJeong, Hu Young-
dc.contributor.nonIdAuthorYokoshima, Tokihiko-
dc.contributor.nonIdAuthorYamauchi, Yusuke-
dc.type.journalArticleArticle-
dc.subject.keywordAuthoralloys-
dc.subject.keywordAuthorelectrochemistry-
dc.subject.keywordAuthormesoporous materials-
dc.subject.keywordAuthorruthenium-
dc.subject.keywordAuthorsurfactants-
dc.subject.keywordPlusMETHANOL OXIDATION REACTION-
dc.subject.keywordPlusHIGHLY-ACTIVE ELECTROCATALYSTS-
dc.subject.keywordPlusAQUEOUS SURFACTANT SOLUTIONS-
dc.subject.keywordPlusPD BIMETALLIC NANODENDRITES-
dc.subject.keywordPlusSIZE-CONTROLLED SYNTHESIS-
dc.subject.keywordPlusHIGH CATALYTIC-ACTIVITY-
dc.subject.keywordPlusFACILE SYNTHESIS-
dc.subject.keywordPlusFUEL-CELLS-
dc.subject.keywordPlusPLATINUM NANOPARTICLES-
dc.subject.keywordPlusSOFT-TEMPLATE-
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