DC Field | Value | Language |
---|---|---|
dc.contributor.author | Cho, Hyeon Mo | ko |
dc.contributor.author | Bok, Kyongjin | ko |
dc.contributor.author | Park, Seo Hyeon | ko |
dc.contributor.author | Lim, Young Mook | ko |
dc.contributor.author | Lee, Myong Euy | ko |
dc.contributor.author | Choi, Moon-Gun | ko |
dc.contributor.author | Lee, Kang Mun | ko |
dc.date.accessioned | 2013-03-12T19:27:09Z | - |
dc.date.available | 2013-03-12T19:27:09Z | - |
dc.date.created | 2012-10-11 | - |
dc.date.created | 2012-10-11 | - |
dc.date.issued | 2012-08 | - |
dc.identifier.citation | ORGANOMETALLICS, v.31, no.15, pp.5227 - 5230 | - |
dc.identifier.issn | 0276-7333 | - |
dc.identifier.uri | http://hdl.handle.net/10203/103286 | - |
dc.description.abstract | Stable 1-bromo-1-silacyclopropanes were synthesized in high yields from the reaction of the stable bromotrisylsilylenoid 1 (trisyl = C(SiMe3)(3)) with olefins such as styrene, trimethylvinylsilane, triethylvinylsilane, and dimethylphenylvinylsilane, a new synthetic route for silacyclopropanes. The structure of bromosilacyclopropane 5 was confirmed by X-ray analysis. In the presence of excess MeOH the phenyl-substituted bromosilacyclopropane 2 underwent regioselective ring opening to give the corresponding product 6. In contrast, the reaction of silyl-substituted bromosilacyclopropane 5 with MeOH gave only the product of nucleophilic substitution at the silicon atom, 1-methoxy-1-silacyclopropane 7, without any ring opening. Furthermore, the bromosilacyclopropane 2 extruded bromosilylene 8 through a thermal cycloreversion reaction. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | MOLECULAR-STRUCTURE | - |
dc.subject | FUNCTIONALIZED SILYLLITHIUMS | - |
dc.subject | PHOTOCHEMICAL GENERATION | - |
dc.subject | SILICON | - |
dc.subject | REACTIVITY | - |
dc.subject | SILYLENE | - |
dc.subject | CHEMISTRY | - |
dc.subject | HEXAMETHYLSILIRANE | - |
dc.subject | DIMETHYLSILYLENE | - |
dc.subject | CHLOROSILYLENE | - |
dc.title | A New Synthetic Route for Silacyclopropanes: Reactions of a Bromosilylenoid with Olefins | - |
dc.type | Article | - |
dc.identifier.wosid | 000307422200003 | - |
dc.identifier.scopusid | 2-s2.0-84865034590 | - |
dc.type.rims | ART | - |
dc.citation.volume | 31 | - |
dc.citation.issue | 15 | - |
dc.citation.beginningpage | 5227 | - |
dc.citation.endingpage | 5230 | - |
dc.citation.publicationname | ORGANOMETALLICS | - |
dc.identifier.doi | 10.1021/om3005349 | - |
dc.contributor.nonIdAuthor | Cho, Hyeon Mo | - |
dc.contributor.nonIdAuthor | Bok, Kyongjin | - |
dc.contributor.nonIdAuthor | Park, Seo Hyeon | - |
dc.contributor.nonIdAuthor | Lim, Young Mook | - |
dc.contributor.nonIdAuthor | Lee, Myong Euy | - |
dc.contributor.nonIdAuthor | Choi, Moon-Gun | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | MOLECULAR-STRUCTURE | - |
dc.subject.keywordPlus | FUNCTIONALIZED SILYLLITHIUMS | - |
dc.subject.keywordPlus | PHOTOCHEMICAL GENERATION | - |
dc.subject.keywordPlus | SILICON | - |
dc.subject.keywordPlus | REACTIVITY | - |
dc.subject.keywordPlus | SILYLENE | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | HEXAMETHYLSILIRANE | - |
dc.subject.keywordPlus | DIMETHYLSILYLENE | - |
dc.subject.keywordPlus | CHLOROSILYLENE | - |
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