DC Field | Value | Language |
---|---|---|
dc.contributor.author | Cho, Kang-Hee | ko |
dc.contributor.author | Na, Kyung-Su | ko |
dc.contributor.author | Kim, Jae-Heon | ko |
dc.contributor.author | Terasaki, Osamu | ko |
dc.contributor.author | Ryoo, Ryong | ko |
dc.date.accessioned | 2013-03-12T12:13:06Z | - |
dc.date.available | 2013-03-12T12:13:06Z | - |
dc.date.created | 2012-08-23 | - |
dc.date.created | 2012-08-23 | - |
dc.date.issued | 2012 | - |
dc.identifier.citation | CHEMISTRY OF MATERIALS, v.24, no.14, pp.2733 - 2738 | - |
dc.identifier.issn | 0897-4756 | - |
dc.identifier.uri | http://hdl.handle.net/10203/102280 | - |
dc.description.abstract | Zeolite beta with a mesopore-micropore hierarchy is hydrothermally synthesized here using various surfactants that can function as a hierarchical structure-directing agent at both the meso- and microstructural levels. Tetraethoxysilane and diatomaceous earth were tested as the silica sources. The pore size distribution of the zeolite was analyzed by N-2 adsorption and electron microscopy. The result was related to the surfactant structure, silica source, and Na+ concentration. The zeolite showed quite uniform mesopores corresponding to the surfactant micelles, in addition to zeolitic micropores generated by the surfactant head groups. Furthermore, an additional level of large pores (>= 20 nm) could be obtained as a result of the retaining of pores from the initial synthesis gel or the zeolite precursor. The large pores were fully retained when the silica source was transformed into a crystalline zeolite via pseudomorphic transformation without migration into the solution phase. The transformation could be controlled by the choice of the synthesis conditions and surfactants. The resultant zeolite with a macropore-mesopore-micropore hierarchy shows potential applicability where facile diffusion is required. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | MESOPOROUS MOLECULAR-SIEVES | - |
dc.subject | CUBIC-P-ZEOLITE | - |
dc.subject | ORGANOSILANE SURFACTANT | - |
dc.subject | HYDROTHERMAL SYNTHESIS | - |
dc.subject | MFI | - |
dc.subject | CONVERSION | - |
dc.subject | NANOSHEETS | - |
dc.subject | CATALYSTS | - |
dc.subject | ARCHITECTURES | - |
dc.subject | GENERATION | - |
dc.title | Zeolite Synthesis Using Hierarchical Structure-Directing Surfactants: Retaining Porous Structure of Initial Synthesis Gel and Precursors | - |
dc.type | Article | - |
dc.identifier.wosid | 000306674200015 | - |
dc.identifier.scopusid | 2-s2.0-84864352633 | - |
dc.type.rims | ART | - |
dc.citation.volume | 24 | - |
dc.citation.issue | 14 | - |
dc.citation.beginningpage | 2733 | - |
dc.citation.endingpage | 2738 | - |
dc.citation.publicationname | CHEMISTRY OF MATERIALS | - |
dc.identifier.doi | 10.1021/cm300841v | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Ryoo, Ryong | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | zeolite | - |
dc.subject.keywordAuthor | hierarchical structure | - |
dc.subject.keywordAuthor | zeolite-structure-directing surfactant | - |
dc.subject.keywordAuthor | pseudomorphic crystallization | - |
dc.subject.keywordPlus | MESOPOROUS MOLECULAR-SIEVES | - |
dc.subject.keywordPlus | CUBIC-P-ZEOLITE | - |
dc.subject.keywordPlus | ORGANOSILANE SURFACTANT | - |
dc.subject.keywordPlus | HYDROTHERMAL SYNTHESIS | - |
dc.subject.keywordPlus | MFI | - |
dc.subject.keywordPlus | CONVERSION | - |
dc.subject.keywordPlus | NANOSHEETS | - |
dc.subject.keywordPlus | CATALYSTS | - |
dc.subject.keywordPlus | ARCHITECTURES | - |
dc.subject.keywordPlus | GENERATION | - |
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