Photochemically Enhanced Selective Adsorption of Gold Ions on Tannin-Coated Porous Polymer Microspheres

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Metal recovery from electronic waste and industrial wastewater has attracted increasing attention to recycle precious metals and inhibit the emission of hazardous heavy metals. However, the selective recovery of precious metals with a large quantity is still very challenging because wastewater contains a variety of different cations while precious metal ions are relatively scarce. Here, we introduce a simple method to selectively increase the adsorption of gold ions using tannin-coated porous polymer microspheres through photochemical reduction. Mesoporous poly(ethylene glycol dimethacrylate-co-acrylonitrile) microspheres with an average pore diameter of 13.8 nm were synthesized and used as an adsorbent matrix. Tannic acid (TA) was deposited onto the internal pores of the polymer matrix by simple immersion in an aqueous milieu. TA coatings increased the maximum number of adsorbed gold ions by 1.3 times because of the well-known metal ion chelation of TA. Under light illumination, the maximum number of adsorbed gold ions dramatically increased by 6.1 times. We examined two distinct mechanisms presumably involved in the enhanced adsorption: the photooxidation of TA and plasmon-induced hot electrons. Moreover, TA-coated microspheres exhibited remarkable selectivity for gold ions among competing metal ions commonly found in waste resources. This work suggests that the photochemically activated TA can serve as an excellent adsorbent for the selective and efficient recovery of gold ions from wastewater.
Publisher
AMER CHEMICAL SOC
Issue Date
2019-06
Language
English
Article Type
Article
Citation

ACS APPLIED MATERIALS & INTERFACES, v.11, no.24, pp.21915 - 21925

ISSN
1944-8244
DOI
10.1021/acsami.9b05197
URI
http://hdl.handle.net/10203/263895
Appears in Collection
MS-Journal Papers(저널논문)EEW-Journal Papers(저널논문)
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