Supramolecular Nanotubules as a Catalytic Regulator for Palladium Cations: Applications in Selective Catalysis

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Despite the recent development of highly efficient and stable metal catalysts, conferral of regulatory characteristics to the catalytic reaction in heterogeneous systems remains a challenge. Novel supramolecular nanotubules were prepared by alternative stacking from trimeric macrocycles, which was found to be able to coordinate with Pd cations. The Pd complexes exhibited a high catalytic performance for C-C coupling reaction. Notably, the tubular catalyst was observed to be controlled by supramolecular reversible assembly and showed superior heterogeneous catalytic activity, which was maintained for a number of cycles or reuse under an aerobic environment. Furthermore, the supramolecular catalyst showed unprecedented selectivity for the multifunctional coupling reaction and was able to serve as a new constructor of asymmetrical compounds.
Publisher
WILEY-V C H VERLAG GMBH
Issue Date
2017-09
Language
English
Article Type
Article
Keywords

ELECTROLESS DEPOSITION; METAL NANOPARTICLES; COUPLING REACTIONS; CARBON; SUBSTRATE; SURFACES; CLUSTERS; SUPPORT; ARRAYS

Citation

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.56, no.38, pp.11511 - 11514

ISSN
1433-7851
DOI
10.1002/anie.201706373
URI
http://hdl.handle.net/10203/226289
Appears in Collection
NT-Journal Papers(저널논문)MS-Journal Papers(저널논문)
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