We present a method that harnesses coherent control capability to two-dimensional Fourier-transform optical spectroscopy. For this, three ultrashort laser pulses are individually shaped to prepare and control the quantum interference involved in two-photon interexcited-state transitions of a V-type quantum system. In experiments performed with atomic rubidium, quantum control for the enhancement and reduction of the 5P(1/2) -> 5P(3/2) transition was successfully tested in which the engineered transitions were distinguishably extracted in the presence of dominant one-photon transitions.